Acta Optica Sinica, Volume. 42, Issue 17, 1732001(2022)

Research Progress of Ultrafast Laser Regulated Nucleation and Growth of Nanocrystals

Ke Sun1, Haiyi Jiang1, Kaiyi Xiong1, Bo Zhang1, Dezhi Tan2、*, and Jianrong Qiu1
Author Affiliations
  • 1College of Optical Science and Engineering, Zhejiang University, Hangzhou 310027, Zhejiang, China
  • 2Zhejiang Lab, Hangzhou 311121, Zhejiang, China
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    Figures & Tables(8)
    Nucleation rate and growth rate varying with temperature[36]
    Optical images of femtosecond laser-induced dots (after annealing) formed at different laser power densities and exposure time[44]. (a) Natural light; (b) 365 nm ultraviolet light (after annealing); (c) transmission electron microscope image; (d) high resolution transmission electron microscope image; (e) size distribution of nanocrystals
    Fluorescence micrographs of lines written by femtosecond laser with pulse energy of 12 μJ, scanning rate of 5 μm/s, and repetition rate in range of 25-200 kHz[47]. (a) Fluorescence photo of written lines without thermal treatment under 365 nm light illumination; (b) photoluminescence spectra of lines written by femtosecond laser in Fig. 3(a); (c) fluorescence photo of written lines under 365 nm light illumination after thermal treatment at 400 ℃ for 5 h; (d) photoluminescence spectra of lines written by femtosecond laser in Fig. 3(c)
    Photoluminescence spectra and luminescence intensity statistics of laser-induced CsPbI3 dots under different repetition rates and pulse widths[48]. (a) Photoluminescence spectra of CsPbI3 dots excited by 405 nm ultraviolet light with laser energy density of 6.4 J·cm-2, pulse width of 230 fs, exposure time of 800 ms and repetition rate range of 75-200 kHz; (b) photoluminescence spectra of CsPbI3 dots excited by 405 nm ultraviolet light with laser energy density of 25.6 J·cm-2, pulse width of 230 fs, exposure time of 800 ms and repetition rate range of 30-200 kHz; (c) full width at half maximum of photoluminescence spectrum varying with repetition frequency in Fig. 4(b); (d) luminescence intensity statistics of laser-induced CsPbI3 dots under different repetition rates and pulse widths; (e) luminescence intensity statistics of CsPbI3 dots excited by 405 nm ultraviolet light with laser energy density of 19.2 J·cm-2, repetition rate of 100 kHz, and pulse width range of 230 fs-5 ps
    Photoluminescence spectra of nanocrystals and corresponding photoluminescence photos[49]. (a) Photoluminescence spectra and corresponding photoluminescence photos of precipitated nanocrystals obtained by ultrafast laser direct writing in Cl-Br-I co-doped perovskite glass; (b) photoluminescence spectra and corresponding photoluminescence photos of precipitated nanocrystals obtained by laser direct writing under different irradiation time
    Principle schematic diagram of ultrafast laser-induced liquid nanophase separation and precipitation of CsPb(Br1-xIx)3 nanocrystals in Br-I co-doped glass[49]
    Encrypted display of nanocrystal patterns in glass and optical storage demonstration. (a) Demonstration of CsPb(Cl/Br)3 nanocrystal erasable pattern in glass for information encryption and decryption[45]; (b) laser-induced nanocrystal optical storage demonstration[49]; (c) (d) laser direct writing color nanocrystal luminescence patterns[49]
    Application of nanocrystal patterned devices[49]. (a) Photographs of micro-LED devices; (b) three-dimensional holographic display
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    Ke Sun, Haiyi Jiang, Kaiyi Xiong, Bo Zhang, Dezhi Tan, Jianrong Qiu. Research Progress of Ultrafast Laser Regulated Nucleation and Growth of Nanocrystals[J]. Acta Optica Sinica, 2022, 42(17): 1732001

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    Paper Information

    Category: Ultrafast Optics

    Received: May. 25, 2022

    Accepted: Jul. 11, 2022

    Published Online: Sep. 16, 2022

    The Author Email: Tan Dezhi (wctdz@zju.edu.cn)

    DOI:10.3788/AOS202242.1732001

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