Journal of Inorganic Materials, Volume. 38, Issue 9, 991(2023)

Research Progress of Inorganic Hole Transport Materials in Perovskite Solar Cells

Yu CHEN1...2, Puan LIN1,2, Bing CAI2,*, and Wenhua ZHANG12,* |Show fewer author(s)
Author Affiliations
  • 11. Southwest Joint Research Institute, School of Materials and Energy, Yunnan University, Kunming 650500, China
  • 22. Institute of Chemical Materials, China Academy of Engineering Physics, Chengdu 610200, China
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    Figures & Tables(9)
    (a) Formal (n-i-p) structure and (b) inverted (p-i-n) structure
    Highest occupied molecular orbital (HOMO) (or valence-band) and lowest unoccupied molecular orbital (LUMO) (or conduction-band) energy levels relative to the vacuum of representative inorganic hole transport materials (HOMO and LUMO of Spiro-OMeTAD for comparison)[18]
    Physical morphology, synthesis process and related properties of nickel-based oxide materials
    Morphology and related properties of copper-based oxide materials
    Physical morphology and related properties of other oxides and non-oxides
    Effect of element doping on device performance
    Effect of additive engineering on device performance
    Effect of interface engineering on device performance
    • Table 1. Properties of inorganic hole transport materials (Spiro-OMeTAD for comparison)

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      Table 1. Properties of inorganic hole transport materials (Spiro-OMeTAD for comparison)

      MaterialHole concentration, N/cm-3Hole mobility, μ/(cm2·V-1·s-1) Conductivity, σ/(S·cm-1)
      Sprio-OMeTAD with Li-TFSI, etc.7.13×1015[19]0.779[19]1.53×10-3[13]
      NiO5.3×1018[20]0.12[20]1.66×10-4[21]
      Cu:NiO7.3×1019[22]~0.2[22]1.25×10-3[23]
      Ni0.8Li0.05Mg0.15O6.46×1018[24]-2.23×10-3[24]
      CuGaO23.098×1019[25]-4.625×10-3[25]
      Zn:CuGaO21.328×1020[25]-1.39×10-2[25]
      CuCrO2-0.1-1.0[26]2.9×10-2[27]
      In:CuCrO27.1×1018[27]0.75[27]6.9×10-2[27]
      CuScO2--2.11×10-3[28]
      CuSCN-1.2×10-3[21]-
      Co3O4-1.49×10-2[29]-
      Co3O4-SrCO3-6.33×10-2[29]-
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    Yu CHEN, Puan LIN, Bing CAI, Wenhua ZHANG. Research Progress of Inorganic Hole Transport Materials in Perovskite Solar Cells[J]. Journal of Inorganic Materials, 2023, 38(9): 991

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    Paper Information

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    Received: Mar. 2, 2023

    Accepted: --

    Published Online: Mar. 6, 2024

    The Author Email: CAI Bing (bingcai@caep.cn), ZHANG Wenhua (wenhuazhang@ynu.edu.cn)

    DOI:10.15541/jim20230105

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