Acta Physica Sinica, Volume. 68, Issue 3, 033101-1(2019)
Figures & Tables(7)
Fig. 1. Potential energy curves of 14 excited states of Sr35Cl. Sr35Cl分子14个激发态的势能曲线
Fig. 2. Permanent dipole moments of 5 bound states of Sr35Cl. Sr35Cl分子5个束缚态的电偶极矩
Fig. 3. Transition dipole moments of 5 bound states of Sr35Cl. Sr35Cl分子5个束缚态的跃迁偶极矩
Table 1.
Spectroscopic constants of the 5 bound states.
5个束缚态的光谱常数
View tableView in ArticleTable 1.
Spectroscopic constants of the 5 bound states.
5个束缚态的光谱常数
Λ-S态 T e/cm−1R e/nm$\omega $ $\omega $ $\chi $ B e/cm−1104 α e/cm−1D e/eVR e附近主要电子组态(%)$ {{\rm{X}}^{2}}\Sigma^+$ 0.0 0.2575 309.78 0.8682 0.1016 4.131 3.703 6 $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ $\text{π}$ 6 ${\rm{\sigma }}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ $\text{π}$ 理论[ 26 ]0.0 0.255 313 0.93 0.1037 — — 实验[ 15 ]0.0 0.257 302[ 27 ]0.95[ 27 ]— — — 实验[ 16 ]0.0 — 302.448 −0.9502 0.1016 4.524 — 实验[ 12 ]0.0 — 302.3 0.950 — — — $ {{\rm{A}}^{2}}\Pi$ 15779.16 0.2518 330.69 — 0.1061 2.013 1.673 6 $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ $\text{π}$ 理论[ 26 ]14730 0.252 323 0.95 0.1055 — — 实验[ 15 ]14818 0.255 309[ 27 ]0.98[ 27 ]— — — 实验[ 16 ]14966.727 — 309.625 0.996 0.1030 4.606 — $ {{\rm{B}}^{2}}\Sigma^+$ 16612.74 0.2538 318.67 0.4874 0.1043 2.599 1.937 6 $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ $\text{π}$ 6 ${\rm{\sigma }}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ $\text{π}$ 理论[ 26 ]15714 0.253 319 0.99 0.1055 — — 实验[ 15 ]15719 0.255 306[ 27 ]0.98[ 27 ]0.1030[ 16 ]— — 实验[ 12 ]15719.5 — 306.4 0.98 — — — — $ {{\rm{C}}^{2}}\Pi$ 33532.99 0.3477 425.57 15.5691 0.0554 −11.932 1.546 6 $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ $\text{π}$ 6 $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ $\text{π}$ 6 $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ 6 $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ $\text{π}$ 理论[ 26 ]26688 0.259 278 0.83 0.1095 — — 实验[ 27 ]26099 — 270 0.72 — — — $ {{\rm{3}}^{2}}\Sigma^+$ 36625.55 0.3519 392.49 10.4544 0.0544 −12.567 1.140 6 $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ $\text{π}$ 6 $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ $\text{π}$ 6 $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ $\text{π}$ 6 $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ $\text{π}$ 6 $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ $\text{π}$ 6 $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ $\text{π}$ 6 $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ $\text{π}$ 6 $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ $\text{π}$ 6 $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{σ}$ $\text{π}$ $\text{π}$ 理论[ 26 ]27979 0.248 358 1.01 0.1095 — — 实验[ 15 ]28822 — 344[ 27 ]1.04[ 27 ]0.1030[ 16 ]— —
Table 2. The
Gv ,Bv andDv of , , , and states of Sr35Cl. Sr35Cl分子 , , , 和 的Gv ,Bv 和Dv 值View tableView in ArticleTable 2. The
Gv ,Bv andDv of , , , and states of Sr35Cl. Sr35Cl分子 , , , 和 的Gv ,Bv 和Dv 值v 0 1 2 3 4 5 6 7 8 9 $ {{\rm{X}}^{2}}\Sigma^+$ Gv /cm−10 308.69 615.44 919.34 1220.80 1520.91 1820.07 2118.05 2414.53 2709.33 Bv /cm−10.101389 0.100964 0.100567 0.100209 0.099815 0.099369 0.098910 0.098467 0.098043 0.097629 108 Dv /cm−14.351839 4.364577 4.467493 4.497514 4.362226 4.242542 4.234360 4.286016 4.334124 4.353049 $ {{\rm{A}}^{2}}\Pi$ Gv /cm−115953.74 16281.83 16598.43 16930.62 17269.01 17605.65 17940.04 18272.59 18603.52 18933.04 Bv /cm−10.106234 0.106462 0.106095 0.105137 0.104604 0.104235 0.103859 0.103475 0.103082 0.102679 108 Dv /cm−14.461909 5.111509 3.253476 3.332790 4.007870 4.130323 4.085546 4.040997 3.976138 3.938946 $ {{\rm{B}}^{2}}\Sigma^+$ Gv /cm−116777.58 17097.77 17402.46 17705.63 18020.44 18339.16 18656.69 18972.44 19286.60 19599.30 Bv /cm−10.104260 0.104168 0.104392 0.103697 0.102831 0.102297 0.101900 0.101515 0.101130 0.100741 108 Dv /cm−14.416717 5.342062 4.947374 3.120903 3.500412 4.129428 4.273733 4.244199 4.206411 4.139361 $ {{\rm{C}}^{2}}\Pi$ Gv /cm−133822.25 34298.68 34607.21 34880.81 35124.57 35352.15 35566.01 35770.85 35971.25 36169.15 Bv /cm−10.056049 0.057354 0.058912 0.059995 0.060974 0.062071 0.063032 0.063843 0.064515 0.065071 108 Dv /cm−10.293093 1.069720 1.371596 2.128287 2.433073 3.023576 3.386636 3.382563 3.426546 3.529599 $ {{\rm{3}}^{2}}\Sigma^+$ Gv /cm−136879.56 37294.02 37638.56 37944.07 38221.43 38480.16 38726.99 38965.82 39199.02 39428.18 Bv /cm−10.055079 0.056481 0.057758 0.059028 0.060242 0.061377 0.062432 0.063414 0.064332 0.065193 108 Dv /cm−10.363052 0.690909 1.002658 1.373820 1.690530 1.922724 2.122355 2.300506 2.453955 2.583320
Table 3. The Franck-Condon factors of the transitions − , − , − and − . Sr35Cl分子 — , — , — 和 — 跃迁的Franck-Condon因子
View tableView in ArticleTable 3. The Franck-Condon factors of the transitions − , − , − and − . Sr35Cl分子 — , — , — 和 — 跃迁的Franck-Condon因子
v ′′ = 01 2 3 4 5 6 7 8 9 $ {{\rm{A}}^{2}}\Pi$ $ {{\rm{X}}^{2}}\Sigma^+ $ v ′ = 00.656888 0.266608 0.062027 0.011563 0.002170 0.000520 0.000163 0.000048 0.000007 0.000000 1 0.272308 0.192420 0.320947 0.150685 0.466479 0.012567 0.033544 0.008655 0.000174 0.000137 2 0.061741 0.365100 0.012591 0.236003 0.200935 0.086356 0.027568 0.007557 0.001791 0.000312 3 0.008378 0.145153 0.330434 0.013476 0.132392 0.200767 0.112395 0.041433 0.012093 0.002903 4 0.000641 0.027499 0.211170 0.231162 0.064589 0.062086 0.184983 0.134977 0.058263 0.018761 5 0.000040 0.003015 0.053925 0.25428 0.132467 0.115528 0.018774 0.155878 0.151198 0.077211 6 0.000004 0.000182 0.008221 0.084623 0.271397 0.058393 0.151118 0.000803 0.117380 0.157174 7 0.000000 0.000021 0.006253 0.016398 0.117920 0.263055 0.014702 0.164939 0.005113 0.077068 8 0.000000 0.000000 0.000052 0.001674 0.027547 0.151418 0.233623 0.000068 0.157208 0.024940 9 0.000000 0.000000 0.000007 0.000118 0.003627 0.041888 0.181283 0.190225 0.008630 0.133109 $ {{\rm{B}}^{2}}\Sigma^+$ $ {{\rm{X}}^{2}}\Sigma^+ $ v ′ = 00.861288 0.125494 0.011927 0.001065 0.000142 0.000047 0.000025 0.000091 0.000000 0.000000 1 0.129692 0.603795 0.220001 0.038332 0.006251 0.001365 0.000411 0.000120 0.000019 0.000000 2 0.008650 0.241321 0.360072 0.284163 0.081308 0.018646 0.004456 0.001109 0.000226 0.000018 3 0.000365 0.027661 0.352567 0.179385 0.288215 0.112584 0.030079 0.007227 0.001600 0.000265 4 0.000002 0.001707 0.051462 0.411903 0.083378 0.268533 0.131641 0.039281 0.009668 0.002055 5 0.000001 0.000017 0.003843 0.078423 0.421433 0.034730 0.246976 0.148790 0.049663 0.012870 6 0.000000 0.000000 0.000117 0.006341 0.108918 0.407382 0.009402 0.221296 0.163711 0.061334 7 8 0.000000 0.000000 0.000003 0.000002 0.000001 0.000007 0.000333 0.000002 0.009581 0.000763 0.141252 0.014168 0.381199 0.173321 0.000074 0.346687 0.190975 0.003801 0.174597 0.158106 9 0.000000 0.000000 0.000000 0.000000 0.000000 0.001272 0.020484 0.203605 0.306437 0.017104 $ {{\rm{C}}^{2}}\Pi$ $ {{\rm{X}}^{2}}\Sigma^+ $ v ′ = 00.000002 0.000057 0.000400 0.002491 0.013257 0.048381 0.121107 0.211164 0.245963 0.199742 1 0.000028 0.000755 0.003923 0.016478 0.054711 0.112499 0.129055 0.063035 0.000478 0.054393 2 0.000216 0.004536 0.018057 0.052861 0.110648 0.119527 0.040456 0.002385 0.059184 0.058927 3 0.000894 0.014294 0.042688 0.083192 0.097065 0.033697 0.003920 0.060262 0.039865 0.000817 $ {{\rm{3}}^{2}}\Sigma^+$ $ {{\rm{X}}^{2}}\Sigma^+ $ v ′ = 00.000005 0.000160 0.001014 0.005583 0.025973 0.082035 0.174625 0.263266 0.237744 0.147940 1 0.000072 0.001726 0.007985 0.028959 0.080861 0.133268 0.106890 0.018946 0.019348 0.137924 2 0.000444 0.008122 0.028147 0.068699 0.114064 0.085695 0.008341 0.025544 0.075168 0.024261 3 0.001887 0.025614 0.064048 0.096749 0.076464 0.007949 0.023664 0.062244 0.010184 0.021472 4 0.005823 0.057375 0.098715 0.079207 0.013459 0.015420 0.056215 0.010480 0.018687 0.044825 5 0.013104 0.091074 0.099009 0.027450 0.005603 0.051927 0.016773 0.012448 0.040966 0.001448 6 0.023467 0.109148 0.062336 0.000039 0.043234 0.033313 0.003366 0.042212 0.004752 0.023015 7 0.036552 0.106016 0.020316 0.019085 0.055807 0.001734 0.035028 0.017051 0.012699 0.031310 8 0.052050 0.085867 0.000431 0.051861 0.028088 0.011562 0.037256 0.000833 0.036176 0.001957 9 0.069548 0.057189 0.008529 0.060907 0.001791 0.038489 0.008713 0.024666 0.015229 0.013407
Table 4. Radiative lifetimes of the transitions − , − and − . Sr35Cl分子 — , — 和 — 跃迁的辐射寿命
View tableView in ArticleTable 4. Radiative lifetimes of the transitions − , − and − . Sr35Cl分子 — , — 和 — 跃迁的辐射寿命
Transition Radiative lifetimes/ns v ′ = 0v ′ = 1v ′ = 2$ {{\rm{A}}^{2}}\Pi $ $ {{\rm{X}}^{2}}\Sigma^+ $ 31.23 31.35 31.56 $ {{\rm{B}}^{2}}\Pi $ $ {{\rm{X}}^{2}}\Sigma^+ $ 38.83 38.89 39.12 $ {{\rm{C}}^{2}}\Pi$ $ {{\rm{X}}^{2}}\Sigma^+ $ 25.92 26.01 26.18
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Dong-Lan Wu, Jin-Hong Yuan, Yu-Feng Wen, Xue-Feng Zeng, An-Dong Xie.
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Received: Sep. 26, 2018
Accepted: --
Published Online: Oct. 28, 2019
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