Laser & Optoelectronics Progress, Volume. 56, Issue 8, 083004(2019)

Identification of Components in Mixtures Based on Raman Spectroscopy

Caizheng Liu1, Qibing Zhu1、*, Min Huang1, and Min Li2
Author Affiliations
  • 1 Key Laboratory of Advanced Process Control for Light Industry, Ministry of Education, Jiangnan University, Wuxi, Jiangsu 214122, China
  • 2 Beijing Zhuoli Hanguang Instrument Co., Ltd., Beijing 101102, China
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    Figures & Tables(7)
    Flow chart of algorithm
    Schematic of overlapping spectrum peaks
    Raman spectra of six kinds of pure substances and mixtures. (a) Pure substance; (b) mixture
    Experimental process. (a) Original spectrum and continuous background; (b) pretreated spectrum
    Peak fitting and decomposition plots. (a) Single peak fitting plot; (b) overlapping peak decomposition plot
    Spectrogram of mixed solution and three kinds of pure substances. (a) Acetone; (b) cyclohexane; (c) ethanol
    • Table 1. Identification results of six kinds of mixtures

      View table

      Table 1. Identification results of six kinds of mixtures

      Pure substanceMixture
      Acetone+cyclohexane+ethanolAcetone+cycloexaneEthanol+cycloexaneAcetoneCyclohexaneEthanol
      Acetone0.81920.84690.00000.96380.00000.0000
      Cyclohexane0.98970.99990.83070.00000.99990.0000
      Ethanol0.87240.65280.87250.00000.63660.8604
      Phosphoric acid0.56470.49460.00000.56330.00000.0000
      MethamphetamineHydrochloride0.55090.51230.40700.44380.37910.2843
      Oxy-6 monoacetylmor-phinehydrochloride0.58170.56420.51570.00000.54230.0000
      Red phosphorus0.48790.48810.00000.53300.00000.0000
      Heroin hydrochloride0.00000.00000.00000.00000.00000.0000
      Nitrogen mustard0.18140.46410.33820.00000.54480.0000
      Diphenyl glycolic acid0.33540.33540.33520.00000.33520.0000
      Mustard gas0.39050.00000.00000.53470.00000.0000
      Tartaric acid0.47740.51480.38960.28240.27990.3896
      Sulfuric acid0.41130.34680.44380.34590.00000.4438
      Sarin0.50030.49860.53220.00000.51210.0000
      Calcium carbonate0.00000.00000.57620.00000.00000.5762
      Nitric acid0.34090.00000.30230.00000.00000.3410
      Acetonitrile0.52590.62340.00000.33520.52060.0000
      Urea0.00000.00000.00000.00000.00000.0000
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    Caizheng Liu, Qibing Zhu, Min Huang, Min Li. Identification of Components in Mixtures Based on Raman Spectroscopy[J]. Laser & Optoelectronics Progress, 2019, 56(8): 083004

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    Paper Information

    Category: Spectroscopy

    Received: Oct. 12, 2018

    Accepted: Nov. 16, 2018

    Published Online: Jul. 26, 2019

    The Author Email: Zhu Qibing (zhuqib@163.com)

    DOI:10.3788/LOP56.083004

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