NUCLEAR TECHNIQUES, Volume. 48, Issue 2, 020303(2025)

Preliminary study on the separation of Technetium from acidic wastewater using NTAamide (C8) extractant

Zhanyuan LIU... Junli WANG, Zhen SHEN, Fangxiang LUO, Taihong YAN, Weifang ZHENG and Hui WANG* |Show fewer author(s)
Author Affiliations
  • Department of Radiochemistry, China Institute of Atomic Energy, Beijing 102413, China
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    Figures & Tables(10)
    Structure of NTAamide(C8) extractant
    At different oxalic acid concentrations ((a) [HNO3]=0.5 mol·L-1) and different nitric acid concentrations((b) [H2C2O4]=0.1 mol·L-1), washing rate of U(Ⅵ), Pu(Ⅳ), Zr(Ⅳ) in the loaded organic phase (color online)
    Flowchart of technetium separation and extraction process
    Concentration distributions of ions in instantaneous of organic phase (a) and aqueous phase (b)
    Concentration distributions of each ion in the organic phase and aqueous phase of each sample(a) Tc(Ⅶ), (b) Pu(Ⅳ), (c) U(VI), Zr(IV), Sr(II), Cs(I), Ru(III)
    Concentration distributions of technetium in the two phases of the effluents (a) and each stage (b)
    • Table 1. Process parameters of cascade experiment

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      Table 1. Process parameters of cascade experiment

      工艺段

      Process section

      工艺参数

      Process parameters

      流量

      Flow rate / mL

      F料液F liquid material0.5 mol·L-1 HNO3, Tc, Pu, U, Zr, Ru, Sr, Cs3
      萃取剂 Extractant0.1 mol·L-1 NTAamide/C12H261
      洗涤剂 Detergent0.1 mol·L-1 HNO3+0.1 mol·L-1 H2C2O40.5
      级数 Stage numbers萃取:8级Extraction: 8,洗涤:8级Washing: 8
    • Table 2. Composition of feed solution

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      Table 2. Composition of feed solution

      组分 ComponentTc(VII)Pu(IV)U(VI)Zr(IV)Sr(II)Cs(I)Ru(III)
      浓度 Concentration / g·L-18.68×10-34.81×10-36.51×10-24.67×10-39.7×10-28.62×10-28.43×10-2
    • Table 3. The concentration of each component in the organic phase

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      Table 3. The concentration of each component in the organic phase

      组分Component锝Tc锶Sr锆Zr钌Ru铯Cs铀U钚Pu
      浓度Concentration / g·L-12.79×10-24.53×10-53.47×10-56.09×10-33.5×10-64.03×10-32.4×10-6
    • Table 4. Purification of coefficient of technetium to interfering metal ions

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      Table 4. Purification of coefficient of technetium to interfering metal ions

      组分Component钚Pu铀U锆Zr钌Ru锶Sr铯Cs
      净化系数 Purification factor6.4×1035.2×1024.3×102456.9×1037.9×104
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    Zhanyuan LIU, Junli WANG, Zhen SHEN, Fangxiang LUO, Taihong YAN, Weifang ZHENG, Hui WANG. Preliminary study on the separation of Technetium from acidic wastewater using NTAamide (C8) extractant[J]. NUCLEAR TECHNIQUES, 2025, 48(2): 020303

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    Paper Information

    Category: NUCLEAR CHEMISTRY, RADIOCHEMISTRY, RADIOPHARMACEUTICALS AND NUCLEAR MEDICINE

    Received: Sep. 6, 2024

    Accepted: --

    Published Online: Mar. 14, 2025

    The Author Email: WANG Hui (WANGHui)

    DOI:10.11889/j.0253-3219.2025.hjs.48.240363

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