Journal of Radiation Research and Radiation Processing, Volume. 41, Issue 1, 010202(2023)

Epoxy-functionalized polyethylene-octene prepared by γ-ray radiation and its application in polyamide 6 toughening modification

Qingru LIANG1... Zhenyan JI2, Chunlei DONG2, Fan ZHANG2, Zhe XING2,**, Yarui AN1, and Guozhong WU23,* |Show fewer author(s)
Author Affiliations
  • 1University of Shanghai Science and Technology, Shanghai 200093, China
  • 2Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China
  • 3Shanghai Tech University, Shanghai 200031, China
  • show less
    Figures & Tables(10)
    Flow chart of POE-g-PGMA preparation
    FTIR Spectra of POE, non-irradiated-POE-GMA and irradiated-POE-g-PGMA
    Fracture-surface morphologies of PA6 and PA6/POE blends with different POE-g-PGMA contents: (a) PA6; (b) G0;(c) G1; (d) G2; (e) G3
    Schematic diagram of mechanical specimens and mechanical property curves of blends with different POE-g-PGMA contents: (a) tensile test specimens; (b) tested tensile test specimena; (c) tensile strength and elongation at break curve; (d) flexural strength and notched impact strength curve
    DSC curves of PA6 and PA6/POE blends with different POE-g-PGMA contents: (a) melting curves; (b) crystallization curves (color online)
    TG curves of PA6 and PA6/POE blends with different POE-g-PGMA contents (color online)
    Interface compatibility diagram of PA6/POE blends with different POE-g-PGMA contents: (a) pure POE, (b) pure POE-g-PGMA, (c) pure PA6, (d) the uncompatibilized G0 blend, and (e) the compatibilized G2 blend
    Hygroscopic coefficient as a function of POE-g-PGMA content in PA6/POE blends: (a) 0~768 h hygroscopic coefficient curve; (b) hygroscopic coefficient curve of different POE-g-PGMA contents at 768 h
    • Table 1. Composition of the samples

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      Table 1. Composition of the samples

      样品

      Sample description

      PA6

      / %

      POE

      / %

      POE-g-PGMA

      / %

      PA610000
      POE01000
      PA6/POE/PG090100

      PA6/POE/PG1

      PA6/POE/PG2

      PA6/POE/PG3

      90

      90

      90

      10

      10

      10

      1

      2

      3

    • Table 2. Thermal properties of the blends from DSC

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      Table 2. Thermal properties of the blends from DSC

      样品 Sample

      Tm

      / °C

      Tc

      / °C

      Hm

      / (J·g-1)

      Hc

      / (J·g-1)

      Crystallinity/%

      Tloss,5%

      / ℃

      PA6221.47167.8260.7356.3724.50382
      POE-----438
      G0221.56185.8952.8962.4427.14400
      G1221.98185.3248.3960.2126.17399
      G2221.40186.4852.0666.6628.97401
      G3221.45185.1446.8255.8824.28405
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    Qingru LIANG, Zhenyan JI, Chunlei DONG, Fan ZHANG, Zhe XING, Yarui AN, Guozhong WU. Epoxy-functionalized polyethylene-octene prepared by γ-ray radiation and its application in polyamide 6 toughening modification[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(1): 010202

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    Paper Information

    Category: Research Articles

    Received: Oct. 14, 2022

    Accepted: Nov. 28, 2022

    Published Online: Mar. 6, 2023

    The Author Email:

    DOI:10.11889/j.1000-3436.2022-0107

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