Journal of Semiconductors, Volume. 44, Issue 3, 032701(2023)

A binder-free CF|PANI composite electrode with excellent capacitance for asymmetric supercapacitors

Kexin Li*, Gentian Yue*, and Furui Tan**
Author Affiliations
  • Henan Key Laboratory of Photovoltaic Materials and Laboratory of Low-Dimensional Materials Science, Henan University, Kaifeng 475004, China
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    Figures & Tables(9)
    The schematic diagram of the CF|PANI composite.
    (Color online) Optical diagram of (a) the CF, (b) CF after electrochemical activation, (c) the CF|PANI3, (d) the CF|PANI3 overcoated with PVA-H2SO4. SEM images of the pretreated CF bundle at (e) 1000, (f) 10 000 and (g) 100 000 magnification; the SEM images of pretreated CF|PANI3 at (h) 1000, (i) 10 000 and (j) 100 000 magnification.
    (Color online) (a) Raman spectrum and (b) XRD spectrum of CF|PANI3.
    (Color online) (a) GCD curves of the different electrodes at 1 A/g condition. (b) CVs for the different electrodes at 20 mV/s condition. (c) EIS for the different electrodes.
    (Color online) (a) GCD curves of CF|PANI3 composite electrode at different current densities. (b) CV curves for the CF|PANI3 composite electrode at low scan rates. (c) CV curves for the CF|PANI3 composite electrode at high scan rates. (d) Cyclic stability and rate performance of the CF|PANI3 composite electrode.
    (Color online) (a) GCD curves of the CP3//CP3 SSC. (b) CV curves of the CP3//CP3 SSC at different voltage windows. (c) EIS of the CP3//CP3 SSC.
    (Color online) (a) GCD of the MM//CP3 ASC under different voltage windows. (b) EIS of the MM//CP3 ASC. (c) CV curves of the MM//CP3 ASC under different voltage windows. (d) Relationships between the energy density and power density of the CP3//CP3 SSC and MM//CP3 ASC. (e) The red, green and yellow LED lamps are lit by two series MM//CP3 ASC.
    • Table 0. Capacitance performance parameters of the CP3//CP3 SSC at different current densities.

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      Table 0. Capacitance performance parameters of the CP3//CP3 SSC at different current densities.

      J (A/g)0.515101520
      Udrop (V)0.0090.020.0970.1830.2730.35
      Δt (s)466.122741.818.911.27.5
      Cs (F/g)235.12231.63231.45231.33231.09230.77
      Ct (F/g)58.7857.9157.8357.8357.7757.69
      E (W·h/kg)8.027.726.555.364.243.39
      P (W/kg)61.93122.49564.371021.231363.151625.01
    • Table 0. TheUdrop andCs values of the CP|PANI2, CP|PANI3, CP|PANI4, and CP|PANI5 electrodes at 1 A/g condition.

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      Table 0. TheUdrop andCs values of the CP|PANI2, CP|PANI3, CP|PANI4, and CP|PANI5 electrodes at 1 A/g condition.

      Composite electrodeCF|PANI2CF|PANI3CF|PANI4CF|PANI5
      Udrop (V)0.010.020.040.06
      Cs (F/g)97.98231.63153.6570.21
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    Kexin Li, Gentian Yue, Furui Tan. A binder-free CF|PANI composite electrode with excellent capacitance for asymmetric supercapacitors[J]. Journal of Semiconductors, 2023, 44(3): 032701

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    Paper Information

    Category: Articles

    Received: Sep. 3, 2022

    Accepted: --

    Published Online: Mar. 30, 2023

    The Author Email: Li Kexin (yuegentian@126.com), Yue Gentian (yuegentian@126.com), Tan Furui (frtan@henu.edu.cn)

    DOI:10.1088/1674-4926/44/3/032701

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