[3] [3] CHENG X B, YAN C, ZHANG X Q, et al. Electronic and ionic channels in working interfaces of lithium metal anodes.［J］. ACS Energy Lett, 2018, 3(7): 1564-1570.

[4] [4] ZHANG R, CHEN X R, CHEN X, et al. Lithiophilic sites in doped graphene guide uniform lithium nucleation for dendrite-free lithium metal anodes.［J］. Angew Chem Int Ed, 2017, 56(27): 7764-7768.

[5] [5] TIKEKAR M D, CHOUDHURY S, TU Z, et al. Design principles for electrolytes and interfaces for stable lithium-metal batteries［J］. Nat Energy, 2016, 1(9): 16114.

[6] [6] WANG H. Artificial solid electrolyte interphase acting as “armor” to protect the anode materials for high-performance lithium-ion battery［J］. Chem Res, 2020, 36(3): 402-409.

[7] [7] YAN C, LI H R, CHEN X, et al. Regulating the inner helmholtz plane for stable solid electrolyte interphase on lithium metal anodes［J］. Am Chem Soc, 2019, 141(23): 9422-9429.

[8] [8] AURBACH D, ZINIGRAD E, COHEN Y, et al. A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions［J］. Solid State Ionics, 2002, 148(3/4): 405-416.

[9] [9] SAWADA Y, DOUGHERTY A, GOLLUB, J P. Dendritic and fractal patterns in electrolytic metal deposits［J］. Phys Rev Lett, 1986, 56(12): 1260.

[10] [10] ROSSO M, CHAZALVIEL J N, CHASSAING E. Calculation of the space charge in electrodeposition from a binary electrolyte［J］. Electroanal Chem, 2006, 587(2): 323-328.

[11] [11] PELED E. The electrochemical behavior of alkali and alkaline earth metals in nonaqueous battery systems-the solid electrolyte interphase model［J］. J Electrochem Soc, 1979, 126(12): 2047.

[12] [12] SHEN X, ZHANG R, CHEN X, et al. The failure of solid electrolyte interphase on Li metal anode: structural uniformity or mechanical strength?［J］. Adv Energy Mater, 2020, 10(10): 1903645.

[13] [13] CHEN X, LI H R, SHEN X, et al. The origin of reduced reductive stability of ion-solvent complexes on alkali and alkaline earth metal anodes［J］. Angew Chem Int Ed, 2018, 57(51): 16643-16647.

[14] [14] LIU X, SHEN X, LUO L, et al. Designing advanced electrolytes for lithium secondary batteries based on the coordination number rule［J］.

[15] [15] YAN C, CHENG X B, YAO Y X, et al. An armored mixed conductor interphase on a dendrite-free lithium-metal anode［J］. Adv Mater, 2018, 30(45): 1804461.

[16] [16] SONG Q, LI A, SHI L, et al. Thermally stable, nano-porous and eco-friendly sodium alginate/attapulgite separator for lithium-ion batteries［J］. Energy Stor Mater, 2019, 22: 48-56.

[17] [17] SUN W, SUN X, AKHTAR N, et al. Attapulgite nanorods assisted surface engineering for separator to achieve high-performance lithium-sulfur batteries［J］. J Energy Chem, 2020, 48: 364-374.

[18] [18] LAN Y, CHEN D. Fabrication of nano-sized attapulgite-based aerogels as anode material for lithium ion batteries［J］. Mater Sci, 2018, 53(3): 2054-2064.

[19] [19] YANG C H, GAO R J, YANG H M, et al. Application of layered nanoclay in electrochemical energy: Current status and future［J］. Energy Chem, 2021, 3(5): 100062.

[20] [20] ZHOU X M, HUANG X Y, XIE A J, et al. V2O5-decorated Mn-Fe/attapulgite catalyst with high SO2 tolerance for SCR of NOx with NH3 at low temperature［J］. Chem Eng J, 2017, 326: 1074-1085.

[22] [22] WEI Q L, XIONG F Y, TANG S S. Porous one-dimensional nanomaterials: Design, fabrication and applications in electrochemical energy storage［J］. Adv Mater, 2017, 29(20): 1602300.

[23] [23] YAO P. PVDF/Palygorskite nanowire composite electrolyte for 4 V rechargeable lithium batteries with high energy density［J］. Nano Lett, 2018, 18(10): 6113-6120.

[24] [24] LU Z, HAO Z, WANG J, et al. Efficient removal of europium from aqueous solutions using attapulgite-iron oxide magnetic composites［J］. J Ind Eng Chem, 2016, 34: 374-381.

[25] [25] LAN Y, CHEN D J. Fabrication of silver doped attapulgite aerogels as anode material for lithium ion batteries［J］. J Mater Sci: Mater Electron, 2018, 29(23): 19873-19879.