Spectroscopy and Spectral Analysis, Volume. 42, Issue 6, 1728(2022)

Study on Detecting Method of Toxic Agent Containing Phosphorus (Simulation Agent) by Optical Emission Spectroscopy of Atmospheric Pressure Low-Temperature Plasma

Jin-chuan YANG1,*... Jing-long AN1,1; 2;, Cong LI3,3;, Wen-chao ZHU3,3; *;, Bang-dou HUANG4,4; *;, Cheng ZHANG4,4; 5; and Tao SHAO4,4; 5; |Show fewer author(s)
Author Affiliations
  • 11. Key Laboratory of Electromagnetic Field and Electrical Apparatus Reliability of Hebei Province, Hebei University of Technology, Tianjian 300130, China
  • 33. State Key Laboratory of NBC Protection for Civilian, Beijing 102205, China
  • 44. Beijing International S&T Cooperation Base for Plasma Science and Energy Conversion, Institute of Electrical Engineering Chinese Academy of Sciences, Beijing 100190, China
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    Figures & Tables(11)
    Three different excitation source experimental devices(a): Nanosecond pulse; (b): DC self-pulse; (c): Microwave
    P atom line and PO molecule band in MW plasma with argon carrier gas
    OES from Microwave plasma before and after DMMP is introduced(a): Before the introduction of the DMMP;(b): After the introduction of the DMMP
    OES of DMMP from nanosecond pulse discharge (a) and DC self-pulse discharge (b)
    Spectra fitting of different excitation sources(a): Microwave; (b): Nanosecond pulse; (c): DC self-pulse
    Principal component analysis diagram
    Linear fitting of frequency and spectral intensity
    • Table 1. Characteristic OES of sarin and DMMP simulant

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      Table 1. Characteristic OES of sarin and DMMP simulant

      来源原子/基团跃迁能级
      沙林/DMMPP(213.82 nm)3s23p2(3P)
      4s3/2→3s23p3 3/2
      沙林/DMMPP(215.09 nm)3s23p2(1D)
      4s5/2→3s23p3 3/2
      沙林/DMMPPO(253.67, 255.6 nm)A2Σ+→X2Π
    • Table 2. Fitting temperature of different excitation sources

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      Table 2. Fitting temperature of different excitation sources

      激励源转动温度Tr/K振动温度Tv/K
      微波1 3002 100
      纳秒脉冲9804 100
      直流自脉冲8803 500
    • Table 3. Comparison of different excitation sources

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      Table 3. Comparison of different excitation sources

      激励源形式特点气氛
      微波无电极谱线纯净氩气
      纳秒脉冲针-针电极本底强烈空气
      直流自脉冲针-针电极本底强烈空气
    • Table 4. Eigenvalues and contribution rate of principal components

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      Table 4. Eigenvalues and contribution rate of principal components

      主成分特征值贡献率/%累计贡献率/%
      PC14.14×101073.573.5
      PC21.04×101018.692.1
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    Jin-chuan YANG, Jing-long AN, Cong LI, Wen-chao ZHU, Bang-dou HUANG, Cheng ZHANG, Tao SHAO. Study on Detecting Method of Toxic Agent Containing Phosphorus (Simulation Agent) by Optical Emission Spectroscopy of Atmospheric Pressure Low-Temperature Plasma[J]. Spectroscopy and Spectral Analysis, 2022, 42(6): 1728

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    Paper Information

    Category: Research Articles

    Received: May. 31, 2021

    Accepted: --

    Published Online: Nov. 14, 2022

    The Author Email: YANG Jin-chuan (yangjinchuan@mail.iee.ac.cn)

    DOI:10.3964/j.issn.1000-0593(2022)06-1728-07

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