Journal of Inorganic Materials, Volume. 35, Issue 3, 309(2020)

C@K2Ti6O13 Hierarchical Nano Materials: Effective Adsorption Removal of Cr(VI)

Mingyu ZHU... Dezhe FAN, Bei LIU, Shuya LIU, Ming FANG* and Xiaoli TAN |Show fewer author(s)
Author Affiliations
  • MOE Key Laboratory of Resources and Environmental System Optimization, North China Electric Power University, Beijing 102206, China
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    Figures & Tables(7)
    (a) SEM image, (b) TEM image, (c) HRTEM image, (d) XRD pattern, (e) N2 adsorption-desorption isotherm and (f) TGA- DTG curves of C@K2Ti6O13 hierarchical nanostructures
    FT-IR spectra of the samples annealed at different temperatures
    Effect of pH and ionic strength on Cr(VI) adsorption
    (a) Effect of contact time on Cr(VI) adsorption onto C@K2Ti6O13 HNMs and (b) corresponding fitting curve by the pseudo-second-order kinetic model
    (a) Adsorption isotherms, (b) Langmuir isotherm model, (c) Freundlich isotherm model, and (d) plot of lnKdvs 1/T of the Cr(VI) on C@K2Ti6O13
    • Table 1. Parameters simulated by Langmuir and Freundlich models of C@K2Ti6O13

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      Table 1. Parameters simulated by Langmuir and Freundlich models of C@K2Ti6O13

      T/KLangmuir modelFreundlich model
      qmbR2nKfR2
      298370.0560.972.72.20.97
      313370.0520.952.72.20.93
      328290.0660.943.22.20.89
    • Table 2. Thermodynamic parameters for Cr(VI) adsorption

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      Table 2. Thermodynamic parameters for Cr(VI) adsorption

      ΔHθ/(kJ·mol-1)ΔSθ/(kJ·K-1·mol-1)ΔGθ/(kJ·mol-1)
      298 K313 K323 K
      0.0750.0124-4.77-4.74-4.75
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    Mingyu ZHU, Dezhe FAN, Bei LIU, Shuya LIU, Ming FANG, Xiaoli TAN. C@K2Ti6O13 Hierarchical Nano Materials: Effective Adsorption Removal of Cr(VI)[J]. Journal of Inorganic Materials, 2020, 35(3): 309

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    Paper Information

    Category: RESEARCH PAPER

    Received: Jul. 22, 2019

    Accepted: --

    Published Online: Jan. 27, 2021

    The Author Email: FANG Ming (mfang@ncepu.edu.cn)

    DOI:10.15541/jim20190370

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