Infrared and Laser Engineering, Volume. 52, Issue 3, 20220470(2023)

Rapid quantitative analysis of ZnGa2O4(GZO) thin films using picosecond laser induced breakdown spectroscopy

Lili Dong1, Qing Gao2, Jiasen Wu2, Xiangyu Xia2, Shiming Liu2, and Junshan Xiu2、*
Author Affiliations
  • 1School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo 255000, China
  • 2School of Physics and Optoelectronic Engineering, Shandong University of Technology, Zibo 255000, China
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    Figures & Tables(12)
    Transmittance of GZO films at different sputtering powers
    Optical band gap widths of GZO films at different sputtering powers
    Schematic diagram of PS-LIBS experimental set up
    Typical LIBS spectra of GZO thin films
    Boltzmann diagram obtained from Ga lines
    Voigt fitting of Ga lines I 403.29 nm
    Intensity variation of Ga lines I 403.29 nm at different positions
    Zn/Ga spectral line intensity ratio and atomic concentration ratio of GZO films at different sputtering powers
    Zn/Ga calibration curves of GZO films at different sputtering powers
    • Table 1. EDS data of GZO films at different sputtering powers

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      Table 1. EDS data of GZO films at different sputtering powers

      Sputtering parametersAtomic concentration ratios
      Power/WZnGaOZn/Ga
      702.539.7887.690.259
      802.329.5888.090.242
      902.7311.6485.630.235
      952.9313.3283.740.220
    • Table 2. Spectral lines of target elements

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      Table 2. Spectral lines of target elements

      ElementNumber of linesWavelength at the peak positions/nm
      Ga I3287.42, 294.36, 403.29
      Zn I3328.23, 330.26, 334.50
    • Table 3. Spectral lines data of Ga using to calculate the plasma temperature

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      Table 3. Spectral lines data of Ga using to calculate the plasma temperature

      ElementsSpectral lines/nmAtomic spectral lines data
      Aki/s−1Ek/eV gk
      Ga I287.421.17×1084.31234
      294.364.02×1084.31312
      403.294.85×1073.07342
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    Lili Dong, Qing Gao, Jiasen Wu, Xiangyu Xia, Shiming Liu, Junshan Xiu. Rapid quantitative analysis of ZnGa2O4(GZO) thin films using picosecond laser induced breakdown spectroscopy[J]. Infrared and Laser Engineering, 2023, 52(3): 20220470

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    Paper Information

    Category: Materials & Thin films

    Received: Nov. 10, 2022

    Accepted: --

    Published Online: Apr. 12, 2023

    The Author Email: Xiu Junshan (xiujunshan@126.com)

    DOI:10.3788/IRLA20220470

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