Journal of Synthetic Crystals, Volume. 53, Issue 10, 1769(2024)

Synthesis, Crystal Structure, Luminescent and Magnetic Properties of Pyridyl Phenyl Substituted Nitronyl Nitroxide Radical-MnII-LnIII Tetranuclear Clusters

LI Baoyi1... HE Min2 and LI Hongdao1,* |Show fewer author(s)
Author Affiliations
  • 1Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China
  • 2School of Chemistry and Chemical Engineering, North University of China, Taiyuan 030051, China
  • show less
    References(22)

    [1] [1] KAHN O. Molecular magnetism[M]. New York: VCH, 1993.

    [2] [2] BOGANI L, WERNSDORFER W. Molecular spintronics using single-molecule magnets[J]. Nature Materials, 2008, 7(3): 179-186.

    [3] [3] GATTESCHI D, FITTIPALDI M, SANGREGORIO C, et al. Exploring the no-man’s land between molecular nanomagnets and magnetic nanoparticles[J]. Angewandte Chemie International Edition, 2012, 51(20): 4792-4800.

    [4] [4] VINCENT R, KLYATSKAYA S, RUBEN M, et al. Electronic read-out of a single nuclear spin using a molecular spin transistor[J]. Nature, 2012, 488(7411): 357-360.

    [5] [5] CANESCHI A, REY P, GATTESCHI D. The chemistry and magnetic properties of metal nitronyl nitroxide complexes[J]. Prog Inorg Chem, 1991, 39: 331-421.

    [6] [6] CANESCHI A, GATTESCHI D, SESSOLI R, et al. Toward molecular magnets: the metal-radical approach[J]. Accounts of Chemical Research, 1989, 22(11): 392-398.

    [7] [7] PREUSS K E. Metal-radical coordination complexes of thiazyl and selenazyl ligands[J]. Coordination Chemistry Reviews, 2015, 289/290: 49-61.

    [8] [8] LI H D, WU S G, TONG M L. Lanthanide-radical single-molecule magnets: current status and future challenges[J]. Chemical Communications, 2023, 59(41): 6159-6170.

    [9] [9] DEMIR S, GONZALEZ M I, DARAGO L E, et al. Giant coercivity and high magnetic blocking temperatures for N23- radical-bridged dilanthanide complexes upon ligand dissociation[J]. Nature Communications, 2017, 8(1): 2144.

    [10] [10] PONETI G, BERNOT K, BOGANI L, et al. A rational approach to the modulation of the dynamics of the magnetisation in a dysprosium-nitronyl-nitroxide radical complex[J]. Chemical Communications, 2007(18): 1807-1809.

    [11] [11] BOGANI L, SANGREGORIO C, SESSOLI R, et al. Molecular engineering for single-chain-magnet behavior in a one-dimensional dysprosium-nitronyl nitroxide compound[J]. Angewandte Chemie International Edition, 2005, 44(36): 5817-5821.

    [12] [12] BERNOT K, BOGANI L, CANESCHI A, et al. A family of rare-earth-based single chain magnets: playing with anisotropy[J]. Journal of the American Chemical Society, 2006, 128(24): 7947-7956.

    [13] [13] FOKIN S, OVCHARENKO V, ROMANENKO G, et al. Problem of a wide variety of products in the Cu(hfac)2-nitroxide system[J]. Inorganic Chemistry, 2004, 43(3): 969-977.

    [14] [14] XU J X, MA Y, LIAO D Z, et al. Four new lanthanide-nitronyl nitroxide (LnIII= PrIII, SmIII, EuIII, TmIII) complexes and a TbIII complex exhibiting single-molecule magnet behavior[J]. Inorganic Chemistry, 2009, 48(18): 8890-8896.

    [15] [15] WANG J, LI J N, ZHANG S L, et al. Syntheses and magnetic properties of a pyrimidyl-substituted nitronyl nitroxide radical and its cobalt(ii) complexes[J]. Chemical Communications, 2016, 52(28): 5033-5036.

    [16] [16] ZHU M, LI Y G, MA Y, et al. Unprecedented nitronyl nitroxide bridged 3d-4f complexes: structure and magnetic properties[J]. Inorganic Chemistry, 2013, 52(21): 12326-12328.

    [17] [17] ZHU M, WANG J J, YANG M, et al. Slow magnetic relaxation in two-dimensional 3d-4f complexes based on phenyl pyrimidyl substituted nitronyl nitroxide radicals[J]. Dalton Transactions, 2015, 44(21): 9815-9822.

    [18] [18] SHELDRICK G M. SHELXS-2014, Program for structure solution[CP]. Gttingen, Germany: Universitt of Gttingen, Germany, 2014.

    [19] [19] SHELDRICK G M. SHELXL-2014, Program for structure refinement[CP]. Gttingen, Germany: Universitt of Gttingen, 2014.

    [20] [20] ALVAREZ S, MENJN B, FALCETO A, et al. Stereochemistry of complexes with double and triple metal-ligand bonds: a continuous shape measures analysis[J]. Inorganic Chemistry, 2014, 53(22): 12151-12163.

    [21] [21] LLUNELL M, CIRERA J, CASANOVA D, et al. SHAPE 2.1 [M]. Barcelona: University of Barcelona, 2013.

    [22] [22] FENG X, LI S H, WANG L Y, et al. A series of lanthanide-organic polymers incorporating ethyl-4, 5-imidazole-dicarboxylato and formate coligand: structures, luminescent and magnetic properties[J]. CrystEngComm, 2012, 14(10): 3684-3693.

    Tools

    Get Citation

    Copy Citation Text

    LI Baoyi, HE Min, LI Hongdao. Synthesis, Crystal Structure, Luminescent and Magnetic Properties of Pyridyl Phenyl Substituted Nitronyl Nitroxide Radical-MnII-LnIII Tetranuclear Clusters[J]. Journal of Synthetic Crystals, 2024, 53(10): 1769

    Download Citation

    EndNote(RIS)BibTexPlain Text
    Save article for my favorites
    Paper Information

    Category:

    Received: May. 28, 2024

    Accepted: Jan. 17, 2025

    Published Online: Jan. 17, 2025

    The Author Email: Hongdao LI (lihong.dao@163.com)

    DOI:

    CSTR:32186.14.

    Topics