Study on the Spectral Identification Characteristics of “Heiqing” and “Heibi”

编号	颜色	光泽	折射率(点测)	相对密度	产地
HQ-1	近黑色	油脂光泽	1.61	2.99	新疆和田
HQ-2	近黑色	油脂光泽	1.61	3.00	新疆和田
XQ	近黑色	油脂光泽	1.61	3.01	青海小灶火
DQ-1	近黑色	油脂光泽	1.61	3.01	新疆大同
DQ-2	近黑色	油脂光泽	1.61	3.01	新疆大同
MB	近黑色	油脂光泽	1.61	2.97	新疆玛纳斯

Table 2. Chemical composition of “Heiqing” and “Heibi” samples(Wt/%)

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Table 2. Chemical composition of “Heiqing” and “Heibi” samples(Wt/%)

样品	HQ-1	HQ-2	XQ	DQ-1	DQ-2	MB
Al₂O₃	0.72	0.68	0.47	0.62	0.67	5.47
SiO₂	57.45	57.25	57.88	57.49	57.26	53.14
K₂O	0.05	0.06	0.04	0.07	0.06	0.02
CaO	12.10	12.34	12.67	12.65	12.42	11.39
NiO	0.01	0.01	0.02	0.02	0	0.06
Cr₂O₃	0	0	0	0.01	0	0.04
Na₂O	0.07	0.06	0.05	0.08	0.07	0.34
MgO	23.75	23.10	23.32	22.53	22.92	15.39
FeO_T	2.74	2.84	2.21	2.98	2.68	8.12
MnO	0.06	0.08	0.04	0.09	0.08	0.09
TiO₂	0.03	0.02	0.02	0.02	0.02	0.14
P₂O₅	0.01	0.01	0.01	0	0	0.02
Total	97	96.46	96.73	96.55	96.18	94.22
Mg/(Fe+ Mg)	94%	94%	95%	93%	94%	77%

Table 3. Partial transition metal ion content of “Heiqing” and “Heibi” samples (μg·g^-1)

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Table 3. Partial transition metal ion content of “Heiqing” and “Heibi” samples (μg·g^-1)

样品	Cr	Ti	Mn	Co	Ni	V
HQ-1	7.69	249.48	727.34	9.30	16.23	7.23
HQ-2	2.50	264.72	723.65	9.59	15.25	7.35
XQ	1.71	200.63	557.95	6.34	7.92	3.88
DQ-1	0.52	221.78	1 502.82	12.91	4.93	14.26
DQ-2	0	236.27	1 520.56	12.77	4.68	14.60
MB	420.06	582.23	955.13	34.23	120.24	203.68

Table 4. Assignments of Raman peaks of “Heiqing” and “Heibi” samples/cm^-1

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Table 4. Assignments of Raman peaks of “Heiqing” and “Heibi” samples/cm^-1

样品	M—OH伸缩振动	Si—O伸缩振动	Si—O—Si 伸缩振动	Si—O 弯曲振动	晶格振动
HQ-1	3 678, 3 665, 3 648	1 058, 1 028, 930	674	528	436, 414, 393, 369, 223, 177, 159, 121
HQ-2	3 678, 3 664, 3 648	1 058, 1 028, 930	674	528	436, 414, 393, 369, 223, 177, 159, 121
XQ	3 678, 3 665, 3 647	1 059, 1 029, 930	674	529	436, 414, 393, 369, 223, 177, 159, 121
DQ-1	3 678, 3 664, 3 648	1 058, 1 028, 930	674	528	436, 414, 393, 369, 223, 177, 159, 121
DQ-2	3 678.1, 3 664.6, 3 648.7	1 058, 1 028, 930	674	528	436, 414, 393, 369, 223, 177, 159, 121
MB	3 677.6, 3 663.7, 3 647.9	1 051, 1 032, 926	669	529	435, 412, 389, 368, 348, 219, 192, 177, 157, 118

Table 5. Assignments of near-Infrared absorption bands of “Heiqing” and “Heibi” samples/nm
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Table 5. Assignments of near-Infrared absorption bands of “Heiqing” and “Heibi” samples/nm
样品 OH的
倍频、
合频 H₂O弯曲振
动与伸缩振
动组合频 Fe—OH Mg—OH
“黑青” 1 379 1 915 2 210 2 310, 2 387, 2 466
“黑碧” 1 400 - - 2 313, 2 394

Table 6. Assignments of Infrared absorption bands of “Heiqing” and “Heibi” samples/cm^-1

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Table 6. Assignments of Infrared absorption bands of “Heiqing” and “Heibi” samples/cm^-1

样品	Si—O伸缩振动	Si—O—Si伸缩振动	Si—O弯曲振动, M—O伸缩振动及OH平动
HQ-1	1 104, 1 061, 1 017, 1 000, 953, 923	757, 686, 662, 644	510, 468, 419
HQ-2	1 105, 1 063, 1 017, 999, 953, 924	757, 686, 662, 644	509, 470, 420
XQ	1 104, 1 062, 1 017, 1 000, 953, 922	756, 686, 662, 644	509, 466, 419
DQ-1	1 104, 1 061, 1 017, 1 000, 953, 923	757, 686, 662, 644	510, 468, 419
MB	1 095, 1 044, 1 000, 960, 922	757, 687, 632	509, 472

Table 7. Comparison of the results of microscopic ultraviolet-visible spectrum and infrared spectrum analysis

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Table 7. Comparison of the results of microscopic ultraviolet-visible spectrum and infrared spectrum analysis

样品	显微紫外-可见光谱/cm^-1			红外光谱/cm^-1
样品	5 225附近	4 800~4 600	4 350~4 300	5 225附近	4 800~4 600	4 350~4 300
“黑青”	5 222	4 717	4 392	5 225	4 738, 4 692	4 349, 4 317
“黑碧”	-	-	4 323	-	4 708	4 307

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Lu-lu DAI, Yan JIANG, Ming-xing YANG. Study on the Spectral Identification Characteristics of “Heiqing” and “Heibi”[J]. Spectroscopy and Spectral Analysis, 2021, 41(1): 292

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Paper Information

Category: Research Articles

Received: Nov. 25, 2019

Accepted: --

Published Online: Apr. 8, 2021

The Author Email: DAI Lu-lu (1289139813@qq.com)

DOI:10.3964/j.issn.1000-0593(2021)01-0292-07

Topics

laser devices and laser physics

Lasers and Laser Optics

Laser physics

laser manufacturing

Instrumentation, Measurement and Metrology

Table 1. The information of the samples

Table 1. The information of the samples

Table 2. Chemical composition of “Heiqing” and “Heibi” samples(Wt/%)

Table 2. Chemical composition of “Heiqing” and “Heibi” samples(Wt/%)

Table 3. Partial transition metal ion content of “Heiqing” and “Heibi” samples (μg·g-1)

Table 3. Partial transition metal ion content of “Heiqing” and “Heibi” samples (μg·g-1)

Table 4. Assignments of Raman peaks of “Heiqing” and “Heibi” samples/cm-1

Table 4. Assignments of Raman peaks of “Heiqing” and “Heibi” samples/cm-1

Table 5. Assignments of near-Infrared absorption bands of “Heiqing” and “Heibi” samples/nm

Table 5. Assignments of near-Infrared absorption bands of “Heiqing” and “Heibi” samples/nm

Table 6. Assignments of Infrared absorption bands of “Heiqing” and “Heibi” samples/cm-1

Table 6. Assignments of Infrared absorption bands of “Heiqing” and “Heibi” samples/cm-1

Table 7. Comparison of the results of microscopic ultraviolet-visible spectrum and infrared spectrum analysis

Table 7. Comparison of the results of microscopic ultraviolet-visible spectrum and infrared spectrum analysis

Table 3. Partial transition metal ion content of “Heiqing” and “Heibi” samples (μg·g^-1)

Table 3. Partial transition metal ion content of “Heiqing” and “Heibi” samples (μg·g^-1)

Table 4. Assignments of Raman peaks of “Heiqing” and “Heibi” samples/cm^-1

Table 4. Assignments of Raman peaks of “Heiqing” and “Heibi” samples/cm^-1

Table 6. Assignments of Infrared absorption bands of “Heiqing” and “Heibi” samples/cm^-1

Table 6. Assignments of Infrared absorption bands of “Heiqing” and “Heibi” samples/cm^-1