Acta Physica Sinica, Volume. 68, Issue 2, 024208-1(2019)
Exploration of the deep-ultraviolet nonlinear optical materials in the derivatives of KBe2BO3F2
Figures & Tables(15)
Fig. 2. Second harmonic generation evolution from KBBF to Pb2BO3I. 从KBBF 到Pb2BO3I的倍频效应演进
Fig. 7. Ball-and-stick representations of Sr2Be2B2O7 and BaAl2B2O7. Sr2Be2B2O7和BaAl2B2O7晶体结构模型
Fig. 8. Ball-and-stick representations of K3Sr3Li2Al4B6O20F and K3Ba3Li2Al4B6O20F (KBLABF). K3Sr3Li2Al4B6O20F和K3Ba3Li2Al4B6O20F (KBLABF)的晶体结构模型
Fig. 11. Crystal structures of the series borates contain B—O covalent bond.层间由B—O共价键连接的系列硼酸盐晶体结构
Table 1.
Cmparison of structural and optical properties of some deep-UV NLO materials of KBBF family with adjacent layers connected by ionic bond and hydrogen bond.
层间含有离子键和氢键连接的类KBBF结构硼酸盐深紫外NLO材料的结构和光学性能比较
View tableView in ArticleTable 1.
Cmparison of structural and optical properties of some deep-UV NLO materials of KBBF family with adjacent layers connected by ionic bond and hydrogen bond.
层间含有离子键和氢键连接的类KBBF结构硼酸盐深紫外NLO材料的结构和光学性能比较
化合物 空间群 结构 层间连接 紫外截止边/nm d eff (KDP)或d ij /pm·V—1注: 上标a为计算值. NaBe2BO3F2[ 20 ]C 2[Be2BO3F2]∞ Na+—F− 155 d eff = 1.7 ×d eff (NH4H2PO4)KBe2BO3F2[ 20 ]R 32[Be2BO3F2]∞ K+—F− 147 d 11 = 0.47 ± 0.01RbBe2BO3F2[ 21 ]R 32[Be2BO3F2]∞ Rb+—F− 160 d 11 = 0.45 ± 0.01CsBe2BO3F2[ 22 ]R 32[Be2BO3F2]∞ Cs+—F− 151 d 11 = 0.5NH4Be2BO3F2[ 48 ]R 32[Be2BO3F2]∞ N—H·F 153 1.2 48 ]R 32[Be2BO3F2]∞ Be2+—F− 144.8 2.3 RbZn2BO3Cl2[ 63 ,81 ]R 32[Zn2BO3Cl2]∞ Rb+—Cl− 198 2.9 KZn2BO3Cl2[ 63 ,81 ]R 32[Zn2BO3Cl2]∞ K+—Cl− 193 3.0 NH4Zn2BO3Cl2[ 63 ]R 32[Zn2BO3Cl2]∞ N—H·Cl 186 2.8 Be2(BO3)F[ 43 ]C 2[Be2BO3F2]∞ Be2+—F− 150a 0.25 BaBe2BO3F3[ 43 ]P 63[Be2BO3F2]∞ Ba2+—F− < 185 0.1 K2Al2B2O7[ 50 ,52 ]P 321[Al3B3O6]∞ Al3+—O2− 180 0.45 K2(1- x )Na2x Al2BO7[88 ](0 <x < 0.6)P 321[Al3B3O6]∞ Al3+—O2− 180 0.45 K2(1− x )Rb2x Al2B2O7[82 ] (0 <x < 0.75)P 321[Al3B3O6]∞ Al3+—O2− — 0.7 K0.67Rb1.33Al2B2O7[ 83 ]P 321[Al3B3O6]∞ Al3+—O2− 188 0.9 51 ]P 321[Al3B3O6]∞ Al3+—O2− < 200 2.0 BaAlBO3F2[ 84 ][AlBO3F2]∞ Ba2+—F− 165 2.0 Rb3Al3B3O10F[ 54 ]P 31c[Al3(BO3)OF]∞ Al3+—F−Al3+—O2− < 200 1.2 BaZnBO3F[ 64 ][ZnBO3F]∞ Zn2+—O2− — 3 × d effBa3Mg3(BO3)3F3[ 87 ]Pna 21[Mg3O2F3(BO3)2]∞ Ba2+—F− 184 d 33 = 0.51
Table 2.
Comparison of structural and optical properties of some deep-UV NLO materials of SBBO family.
SBBO型硼酸盐深紫外NLO材料的结构和光学性能比较
View tableView in ArticleTable 2.
Comparison of structural and optical properties of some deep-UV NLO materials of SBBO family.
SBBO型硼酸盐深紫外NLO材料的结构和光学性能比较
化合物 空间群 结构 层间连接 紫外截止边/nm 倍频效应(KDP)或 d ij/ /pm·V−1Sr2Be2B2O7[ 39 ][Be2(BO3)2O]∞ Sr2+—O2− 155 2.5 Ba2Be2B2O7[ 40 ,73 ][Be2(BO3)2O]∞ Ba2+—O2− 215 2.0 BaAl2B2O7[ 52 ]R 32[Al6B6O12]∞ Al3+—O2− — d 11 = 0.75NaCaBe2B2O6F[ 41 ]Cc [Be3B3O6F3]∞ Ca2+—O2− 190 0.3 K3Ba3Li2Al4B6O20F[ 55 ][Li2Al4B6O20F]∞ Ba2+—O2− 190 1.5 Rb3Ba3Li2Al4B6O20F[ 89 ][Li2Al4B6O20F]∞ Ba2+—O2− 195 1.4 K3Sr3Li2Al4B6O20F[ 57 ]R 32[Li2Al4B6O20F]∞ Sr2+—O2− 190 1.7 (0.9) Cs2Al2(B3O6)2O[ 90 ]P 63[Al2(B3O6)2O] Al3+—O2− 185 d 31 = 0.032
Table 3.
Comparison of structural and optical properties of some fluorooxoborates deep-UV NLO materials.
部分氟化硼酸盐深紫外NLO材料的结构和光学性能比较
View tableView in ArticleTable 3.
Comparison of structural and optical properties of some fluorooxoborates deep-UV NLO materials.
部分氟化硼酸盐深紫外NLO材料的结构和光学性能比较
化合物 空间群 结构 层间连接方式 紫外截止边/nm 倍频效应(KDP) NH4B4O6F[ 69 ]P 21na [B4O6F]∞ N—H·F 156 3.0 CsB4O6F[ 71 ]P 21na [B4O6F]∞ Cs+—F− 155 1.9 RbB4O6F[ 70 ]Pna 21[B4O6F]∞ Rb+—F− < 190 0.8 CsKB8O12F2[ 70 ]P 321[B4O6F]∞ Cs/K+—F− < 190 1.9 CsRbB8O12F2[ 70 ][B4O6F]∞ Cs/K+—F− < 190 1.1 NaB4O6F[ 72 ]C 2[B4O6F]∞ Na+—F− < 180 0.9 SrB5O7F3[ 98 ]Cmc 21[B5O7F3]∞ Sr2+—F− < 180 1.6 Sr2B10O14F6[ 99 ]< 200 2.5 CaB5O7F3[ 97 ]Cmc 21[B5O7F3]∞ Ca2+—F− < 180 2.0 Ca2B10O14F6[ 99 ]< 200 2.3
Table 4.
Comparison of structural and optical properties of some deep-UV NLO materials of KBBF family with adjacent layers connected by rigid B—O groups.
层间含有B—O共价键连接的类KBBF结构硼酸盐深紫外NLO材料的结构和光学性能比较
View tableView in ArticleTable 4.
Comparison of structural and optical properties of some deep-UV NLO materials of KBBF family with adjacent layers connected by rigid B—O groups.
层间含有B—O共价键连接的类KBBF结构硼酸盐深紫外NLO材料的结构和光学性能比较
化合物 空间群 结构 层间连接方式 紫外截止边/nm 倍频效应(KDP) 44 ]Pmn 21[Be2BO5]∞ [BO2]∞ < 200 0.75 44 ]P 21[Be2BO5]∞ [B3O6] < 200 0.68 RbBe2B3O7[ 44 ]Pmn 21[Be2BO5]∞ [BO2]∞ < 200 0.79 Na2CsBe6B5O15[ 45 ]C 2[Be2BO5]∞ [BO3] < 200 1.17 Na2Be4B4O11[ 46 ]P 1[Be2BO5]∞ [B2O5] 171 1.30 LiNa5Be12B12O23[ 46 ]Pc [Be2BO5]∞ [B2O5] 169 1.40 Li4Sr(BO3)2[ 67 ]Cc [SrBO3]∞ [B2O3] 186 2.00
Tools
Get Citation
Copy Citation Text
Min-Qiang Gai, Ying Wang, Shi-Lie Pan. Exploration of the deep-ultraviolet nonlinear optical materials in the derivatives of KBe2BO3F2[J]. Acta Physica Sinica, 2019, 68(2): 024208-1
Paper Information
Category: Research Articles
Received: Dec. 6, 2018
Accepted: --
Published Online: Sep. 29, 2019
The Author Email:
© Copyright 2018-2021 | Chinese Laser Press.
All Rights Reserved 沪ICP备15018463号-20