Laser & Optoelectronics Progress, Volume. 58, Issue 17, 1700002(2021)

Which Metal Nanoparticles Should be Used to Improve the Efficiency of Silicon Thin-Film Solar Cells?

Hailong Li1,2, Shengyi Yang1,2、*, Zhenheng Zhang1,2, Jinming Hu1,2, Yurong Jiang2,3, and Libin Tang4
Author Affiliations
  • 1School of Physics, Beijing Institute of Technology, Beijing 100081, China
  • 2Beijing Key Laboratory of Nanophotonics and Ultrafine Optoelectronic Systems, Beijing 100081, China
  • 3School of Optics and Photonics, Beijing Institute of Technology, Beijing 100081, China
  • 4Kunming Institute of Physics, Yunnan , Kunming 650223, China
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    Figures & Tables(11)
    Si solar cells decorated with Au nanoparticles[54]. (a) Schematic of Si solar cells decorated with Au nanoparticles;(b) photocurrent response for Si solar cells in the absence of nanoparticles, and decorating with Au nanoparticles of 50, 80, and 100 nm in diameter
    Silicon thin-film solar cells with binate Ag nanoparticles [20]. (a) Schematics of the simulated silicon solar cell with spherical silver nanoparticle on silicon surface and inside the silicon; (b) absorption spectra of silicon solar cell without nanoparticles and with two spherical nanoparticles at the top side of the cell and embedded binate nanoparticles
    Silicon solar cell with different shapes of nanoparticles (clustering pyramidal-shaped Ag nanoparticles, clustering spherical-shaped Ag nanoparticles, clustering conical-shaped Ag nanoparticles, and clustering cylindrical-shaped Ag nanoparticles)[67]. (a) Schematics of simulated silicon solar cell; (b) absorption spectra of silicon solar cell
    a-Si∶H thin-film solar cell modified by metal nanoparticles [74]. (a) Schematic of a-Si∶H solar cell with metal nanoparticles; (b) absorption spectra of solar cell embedded with Al, Ag, Au and Cu nanoparticles, here “no NP” indicates the absorption spectrum without nanoparticles
    Solar cell with In NPs and TiO2 space layer on the front surface and Ag NPs on the rear surface[16].(a) Schematic of silicon solar cell with Ag on the rear surface, and In nanoparticles and TiO2 space layer on the front surface; (b) I-V curves of bare solar cell and the solar cell with Ag NPs on the rear surface; (c) I-V curves of the solar cell with Ag NPs on the rear surface and the solar cell with In NPs and TiO2 space layer on the front surface and Ag NPs on the rear surface; (d) I-V curves of bare solar cell and the solar cell with In NPs and TiO2 space layer on the front surface and Ag NPs on the rear surface
    Solar cell with hybrid light-trapping structure[5]. (a) Schematic of front and rear surfaces of the proposed solar cell; (b) I-V curves of the solar cells with and without hybrid light-trapping structure
    Schematic of an n-Si solar cell with SiO2/TiN as the rear contact[88]. (a) Schematic of an n-Si solar cell with TiN as the rear contact; (b) I-V curves of the devices with different rear contact materials of Al,TiN, and SiO2/TiN, where the inset shows an PL image of the cell with a SiO2/TiN contact
    Solar cells with other light-trapping structures. (a) Schematic of the silicon solar cell with nano-conical upper and lower surface[10]; (b) schematic of the silicon solar cell with Ag-SiO2 core-shell hemispherical nanoparticles and metal triangle-like back gratings[43]; (c) schematic of the silicon solar cell with nanostructured dielectric layer of SiNx on top of c-Si[89]; (d) schematic of the silicon solar cell with nanopyramid and metal nanoparticles[90]; (e) schematic of the silicon solar cell with TiN nanogratings[2]; (f) schematic of the silicon solar cell with Al-Cu nanogratings[42]
    • Table 1. Comparison for device performance of silicon solar cells with different metal nanoparticles

      View table

      Table 1. Comparison for device performance of silicon solar cells with different metal nanoparticles

      Cell designOpen-circuit voltage Voc /VShort-circuit current density Jsc /(mA·cm-2Filling factorEfficiency η /%Ref.
      ITO/Au(NPs)/SiO20.859.580.7796.3658
      Au(NPs)-doped SiO2/p-Si0.4610.160.685.2859
      SiO2/TiO2/Si/Ag(NPs)/Si/Al/SiO20.62631.570.8216.1866
      Si/Al(NPs)@Al2O3 core-shell0.58300.621175
      In(NPs)/TiO2/p-Si/Ag(NPs)0.543.93-13.0216
      SiO2+ITO(NPs)/n-Si/p-Si/Al0.55430.410.74712.5879
      SiO2/In(NPs)/SiO2/Si0.52535.090.761480
    • Table 2. Performance of silicon solar cells with different nanostructure reported in Ref.[90]

      View table

      Table 2. Performance of silicon solar cells with different nanostructure reported in Ref.[90]

      Cell designVoc /VJsc /(mA·cm-2Filling factorη /%
      Planar solar cell0.6415.150.7967.68
      Periodic nanopyramid array on the top of silicon substrate0.5419.740.838.89
      Al nanoparticles at rear end of silicon substrate0.5625.910.7811.32
    • Table 3. Comparison for device performance of silicon solar cells with different nanostructures

      View table

      Table 3. Comparison for device performance of silicon solar cells with different nanostructures

      Cell designVoc /VJsc /(mA·cm-2Filling factorη /%Ref.
      Al2O3/SiNx/p-Si/n-Si/SiO2/TiO2/Al0.67639.60.80721.687
      SiO2/TiN/n-Si0.64437.90.8192088
      SiNx/Al2O3/p-Si/n-Si/TiOx/LiF/Al0.6640.80.7921.331
      Si nanocone/planar Si/Si nanocone0.7936.6-24.910
      SiNx nanocone/c-Si0.5728.150.71311.4489
      ITO/PEDOT∶PSS/Si nanopyramid/c-Si/Al(NPs)/Al0.5625.910.7811.3290
      Si/TiN nanograting0.5826.460.82812.272
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    Hailong Li, Shengyi Yang, Zhenheng Zhang, Jinming Hu, Yurong Jiang, Libin Tang. Which Metal Nanoparticles Should be Used to Improve the Efficiency of Silicon Thin-Film Solar Cells?[J]. Laser & Optoelectronics Progress, 2021, 58(17): 1700002

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    Paper Information

    Category: Reviews

    Received: Oct. 20, 2020

    Accepted: Jan. 2, 2021

    Published Online: Sep. 1, 2021

    The Author Email: Yang Shengyi (syyang@bit.edu.cn)

    DOI:10.3788/LOP202158.1700002

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