Spectroscopy and Spectral Analysis, Volume. 42, Issue 7, 2175(2022)

UV Aging Characterization of Paraloid Acrylic Polymers for Art Conservation by Infrared Spectroscopy

Xin GONG1; 2;... Xiang-na HAN1; *; and Kun-long CHEN1; |Show fewer author(s)
Author Affiliations
  • 1. Institute of Cultural Heritage and History of Science & Technology, University of Science and Technology Beijing, Beijing 100083, China
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    Figures & Tables(8)
    Color change and glossiness at 20 degrees of the Paraloid products during UV aging test
    FTIR spectra during UV aging test of Paraloid B-44
    FTIR spectra during UV aging test of Paraloid B-48N
    FTIR spectra during UV aging test of Paraloid B-67
    FTIR spectra during UV aging test of Paraloid B-72
    • Table 1. Basic information of the Paraloid productsa

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      Table 1. Basic information of the Paraloid productsa

      ParaloidTg
      /℃
      单体组成b分子量(Mw)pH体积密度25 ℃
      /(lb·gal-1)
      努氏硬度
      /KHN
      粘度25 ℃
      /Cp
      B-4460MMA/EA140 0001~29.415~161 500
      B-48N50MMA/BMA250 00010~129.111~128 500
      B-6750iBMA60 0003~47.311~121 500
      B-7240EMA /MA105 0003~49.610~114 000
    • Table 2. Carbonyl index (CI) of the Paraloid products at different UV irradiation time

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      Table 2. Carbonyl index (CI) of the Paraloid products at different UV irradiation time

      材料
      名称
      羰基指数(CI)
      0 h336 h1 680 h2 352 h3 864 h
      B-443.423.193.1753.1233.189
      B-48N3.3823.3862.8663.1323.209
      B-672.9212.8622.812.7132.818
      B-724.0943.5583.533.6033.335
    • Table 3. The change of infrared absorption intensity (Dt) of carbonyl group at different UV irradiation time (t)

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      Table 3. The change of infrared absorption intensity (Dt) of carbonyl group at different UV irradiation time (t)

      材料
      名称
      C=O (1 721~1 723 cm-1) 红外吸收强度(Dt/%)
      0336 h1 680 h2 352 h3 864 h
      B-440.00-29.69-30.86-37.41-36.97
      B-48N0.00-19.58-26.54-27.18-32.20
      B-670.00-12.11-42.19-51.37-51.95
      B-720.00-7.751.59-10.54-5.96
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    Xin GONG, Xiang-na HAN, Kun-long CHEN. UV Aging Characterization of Paraloid Acrylic Polymers for Art Conservation by Infrared Spectroscopy[J]. Spectroscopy and Spectral Analysis, 2022, 42(7): 2175

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    Paper Information

    Category: Orginal Article

    Received: Jul. 7, 2021

    Accepted: --

    Published Online: Nov. 16, 2022

    The Author Email:

    DOI:10.3964/j.issn.1000-0593(2022)07-2175-06

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