Journal of Inorganic Materials, Volume. 35, Issue 2, 193(2020)

Thiohydroxy-functionalized Mesoporous Materials: Preparation and its Adsorption to Cr6+

Fu-Qiang CHENG... Tian-Tian JI, Min XUE*, Zi-Hui MENG and Yu-Kai WU |Show fewer author(s)
Author Affiliations
  • School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China
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    Figures & Tables(11)
    Morphologies of SBA-15 and thiohydroxy-functionalized mesoporous material SBA-15-SH
    FT-IR spectra of the as-prepared mesoporous materials
    Effect of solution pH on Cr6+ adsorption by SBA-15-SH
    Effect of environment temperature on Cr6+ adsorption by SBA-15-SH
    Adsorption kinetic study of SBA-15/SBA-15-SH on Cr6+ adsorption
    Effect of the initial concentration of Cr6+ on its adsorption
    Effect of adsorbent dosage on Cr6+ adsorption
    Chelation mechanism of sulfhydryl group and heavy metal ions
    • Table 1. Adsorption kinetics fitting results

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      Table 1. Adsorption kinetics fitting results

      Adsorption equationkqe/(mg·g-1)R2
      Lagergren first order equation$In(q_{e}- q_{1})= Inq_{e}-kt$0.3515.7370.9662
      Lagergren second order equation$\frac{t}{q_{t}}=\frac {1}{kq^{2}_{e}}+\frac {t}{q_{e}}$1.44×10-46.9300.9950
    • Table 2. Isothermal adsorption data fitting

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      Table 2. Isothermal adsorption data fitting

      Isothermal modelKqm1/nR2
      Langmuir$\frac{c_{e}}{q_{e}}=\frac{c_{e}}{q_{m}}+\frac{1}{Kq_{m}}$2.896.86-0.9899
      Freundlich$Inq_{e}= InK_{F}+\frac{Inc_{e}}{n}$--1.8490.7494
    • Table 3. Determination of Cr6+ in spiked real water sample

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      Table 3. Determination of Cr6+ in spiked real water sample

      SampleAdded/(mg·L-1)Found/(mg·L-1)Recovery/%
      Tapwater00.01-
      0.20.2095
      0.50.5098
      1.00.9796
      Industry waste water00.20-
      0.20.41105
      0.50.6896
      1.01.21101
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    Fu-Qiang CHENG, Tian-Tian JI, Min XUE, Zi-Hui MENG, Yu-Kai WU. Thiohydroxy-functionalized Mesoporous Materials: Preparation and its Adsorption to Cr6+[J]. Journal of Inorganic Materials, 2020, 35(2): 193

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    Paper Information

    Category: RESEARCH PAPER

    Received: Mar. 11, 2019

    Accepted: --

    Published Online: Jan. 27, 2021

    The Author Email: XUE Min (minxue@bit.edu.cn)

    DOI:10.15541/jim20190103

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