Acta Physica Sinica, Volume. 69, Issue 6, 064204-1(2020)

High precision calibration of spectral parameters of CO at 1567 nm based on wavelength modulation-direct absorption spectroscopy

Zhen Wang, Yan-Jun Du, Yan-Jun Ding, and Zhi-Min Peng*
Author Affiliations
  • State Key Laboratory of Power Systems, Department of Energy and Power Engineering, Tsinghua University, Beijing 100084, China
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    Figures & Tables(6)
    System schematic diagram of WM-DAS and CW-CRDS. LC, laser current and temperature controller; FI, fiber isolator; AOM, acousto-optic modulator; APD, avalanche photodiode; PD, photodiode; DDG, digital delay generator; PZT, piezoelectric transducer; WM, wavelength meter.
    Measured transmitted intensities of 100 periods of sinusoidal waves and fitted frequency (FSR, free spectral range), and fast Fourier transform (FFT) coefficients Ak and Bk of transmitted light intensity.
    Measured absorption function of CO and the best fits of Voigt and Rautian profile (XCO, c, τ, and σSD represent the CO concentration, light velocity, ring down time and standard deviation of the residual, respectively): (a) WM-DAS; (b) CW-CRDS.
    Measured spectral parameters for various pressures (WM-DAS (red), CW-CRDS (black)): (a) γc (dot); (b) β (square), γ2 (triangle).
    Allan variance measured by the two methods.
    • Table 1. Measured spectroscopic parameters and uncertainties.

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      Table 1. Measured spectroscopic parameters and uncertainties.

      v0/cm–1TransitionE′′/cm–1ϕγ0(T0)/10–2 cm–1·atm–1β0(T0)/10–2 cm–1·atm–1γ2(T0)/10–2 cm–1·atm–1
      CRDSWMHTCRDSWMCRDSWM
      注: WM代表WM-DAS, HT表示HITRAN[36];a表示相同温度(T0 = 288 K)下HITRAN的数据, 空气为背景气;b不确定度 0—1%;c不确定度 5%—15%;d不确定度 10%—20%.
      6371.299R557.670VP6.26b6.23b6.29a
      GP6.43b6.48b2.84c2.90d
      RP6.47b6.50b2.57c2.67d
      SDVP6.50b6.55b0.87c0.77d
      6374.406R680.735VP6.10b6.08b6.12a
      GP6.20b6.30b2.65c2.71d
      RP6.25b6.30b2.38c2.46d
      SDVP6.26b6.36b0.69c0.73d
      6377.407R7107.642VP5.97b5.94b5.99a
      GP6.07b6.12b2.22c2.48d
      RP6.10b6.17b2.06c2.36d
      SDVP6.25b6.24b0.71c0.71d
      6380.301R8138.390VP5.89b5.88b5.89a
      GP6.04b6.02b2.20c2.27d
      RP6.06b6.09b2.14c2.14d
      SDVP6.11b6.15b0.70c0.64d
      6383.090R9172.978VP5.80b5.78b5.80a
      GP5.91b6.03b2.08c2.11d
      RP5.94b6.03b1.89c1.85d
      SDVP5.97b6.09b0.61c0.63d
      6385.771R10211.404VP5.72b5.68b5.73a
      GP5.91b5.89b2.27c2.29d
      RP5.92b5.91b1.98c1.86d
      SDVP5.98b5.96b0.62c0.65d
      6388.347R11253.667VP5.62b5.58b5.67a
      GP5.91b5.80b2.62c2.21d
      RP5.93b5.82b2.15c2.00d
      SDVP5.95b5.89b0.77c0.67d
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    Zhen Wang, Yan-Jun Du, Yan-Jun Ding, Zhi-Min Peng. High precision calibration of spectral parameters of CO at 1567 nm based on wavelength modulation-direct absorption spectroscopy[J]. Acta Physica Sinica, 2020, 69(6): 064204-1

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    Paper Information

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    Received: Dec. 9, 2019

    Accepted: --

    Published Online: Nov. 19, 2020

    The Author Email:

    DOI:10.7498/aps.69.20191865

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