Journal of Inorganic Materials, Volume. 39, Issue 1, 81(2024)

Graphene Based Mesoporous Manganese-Cerium Oxides Catalysts: Preparation and Low-temperature Catalytic Reduction of NO

Yanli WANG, Xinyi QIAN, Chunyin SHEN, and Liang ZHAN
Author Affiliations
  • State Key Laboratory of Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
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    Figures & Tables(14)
    Preparation of G@MnOx-CeO2 catalyst
    NO conversions at different reaction temperatures over various catalysts
    NO conversions over G@MnOx-CeO2 catalysts with different metal loadings
    (a) Nitrogen adsorption/desorption isotherm and (b) corresponding pore size distribution curve of G@SiO2 template
    (a) Nitrogen adsorption/desorption isotherms and (b) corresponding pore size distribution curves of G@MnOx-CeO2 catalysts with different metal loadings
    SEM images of G@Mn(0.35)Ce(0.9) catalyst
    (a-d) TEM images, (e-i) TEM image and corresponding C, Mn, Ce, O element mappings for selected area of G@Mn(0.35)Ce(0.9) catalyst
    XRD patterns of different samples
    Raman spectra of G@Ce(0.9) and G@Mn(0.35)Ce(0.9) catalysts
    XPS spectra of G@Mn(0.35)Ce(0.9) catalyst
    Cyclic NO removal activity of G@Mn(0.35)Ce(0.9) catalyst
    SEM images of G@SiO2 mesoporous template
    • Table 1. Pore parameters of various catalysts

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      Table 1. Pore parameters of various catalysts

      SampleSBET/(m2·g-1) Vtotal/(cm3·g-1) Averagepore size/nm
      G@Ce(0.9)65.00.1257.67
      G@Mn(0.18)Ce(0.45)241.20.2303.81
      G@Mn(0.35)Ce(0.9)197.50.2875.82
      G@Mn(1)Ce(2.7)126.60.1996.29
    • Table 2. Surface atomic concentrations of G@Mn(0.35)Ce(0.9) catalyst

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      Table 2. Surface atomic concentrations of G@Mn(0.35)Ce(0.9) catalyst

      SampleSurface atomic concentration/%Relative atomic ratio/%
      COMnCeOβ/O (Mn3++Mn4+)/Mn
      G@Mn(0.35)Ce(0.9)18.1065.728.267.9245.280.1
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    Yanli WANG, Xinyi QIAN, Chunyin SHEN, Liang ZHAN. Graphene Based Mesoporous Manganese-Cerium Oxides Catalysts: Preparation and Low-temperature Catalytic Reduction of NO[J]. Journal of Inorganic Materials, 2024, 39(1): 81

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    Paper Information

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    Received: May. 11, 2023

    Accepted: --

    Published Online: Mar. 28, 2024

    The Author Email:

    DOI:10.15541/jim20230229

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