Acta Photonica Sinica, Volume. 54, Issue 2, 0231004(2025)
Quantum Cutting Mechanism and Efficiency in Tm3+/Yb3+ -doped NaLu(WO4)2 Phosphors
Fig. 1. XRD patterns of NaLu(WO4)2∶x mol% Tm3+ (x=0.5~50.0), and NaLu(WO4)2∶1.0 mol% Tm3+, y mol% Yb3+ (y=0.5~20.0) samples and the standard data reported in JCPDS card No. 27-0729
Fig. 2. Excitation spectra for NaLu(WO4)2:x mol% Tm3+ (x=0.5~50.0) samples by monitoring 796 nm emission
Fig. 3. Emission spectra of NaLu(WO4)2:x mol% Tm3+ (x=~50.0) phosphors under 279 nm excitation
Fig. 4. 300~900 nm emission spectra, and 700~1 200 nm emission spectra for NaLu(WO4)2∶1 mol% Tm3+/y mol% Yb3+ (y=0~20.0) phosphors under 279 nm excitation
Fig. 5. Fluorescence decays of 1D2, 1G4, 3F2, 3, and 3H4 levels of Tm3+ in NaLu(WO4)2∶1.0 mol% Tm3+/y mol% Yb3+(y=0~20.0) phosphors
Fig. 6. Energy level diagram and quantum cutting routes of Tm3+ and Yb3+ co-doped NaLu(WO4)2 phosphors
Fig. 7. Dependences of energy transfer ET1 efficiency, energy transfer ET2 efficiency, quantum efficiency of 2F5/2 level of Yb3+ and quantum cutting efficiency on Yb3+ concentration
Fig. 8. Fluorescence decays for 2F5/2→2F7/2 transition of Yb3+ in NaLu(WO4)2∶1 mol% Tm3+/y mol%Yb3+(y=0.5,1.0,5.0,10.0,20.0)phosphors
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Mei YANG, Duan GAO, Xuezhu SHA, Xin CHEN, Li WANG, Yanqiu ZHANG, Xiangqing ZHANG, Baojiu CHEN. Quantum Cutting Mechanism and Efficiency in Tm3+/Yb3+ -doped NaLu(WO4)2 Phosphors[J]. Acta Photonica Sinica, 2025, 54(2): 0231004
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Received: Aug. 1, 2024
Accepted: Sep. 14, 2024
Published Online: Mar. 25, 2025
The Author Email: CHEN Baojiu (bjchen@dlmu.edu.cn)