Journal of Inorganic Materials, Volume. 39, Issue 5, 509(2024)

Flame-retardant Properties and Transformation of Flame-retardant Mechanisms of EVA: Effect of ATH/ADP Ratio

Bo CHENG... Xiaohang AN, Dinghua LI* and Rongjie YANG |Show fewer author(s)
Author Affiliations
  • National Engineering Research Center of Flame Retardant Materials, School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
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    Figures & Tables(11)
    Flow chart of EVA composites preparation
    Photos of samples EVA5 (up) and EVA7 (down) for the UL-94 test
    (a) HRR, (b) THR, (c) SPR, and (d) TSR curves of EVA composites
    (a) TG and (b) DTG curves of ATH, ADP, EVA and EVA composites
    Digital images of char after CONE test for EVA1, EVA5, EVA7, and EVA10 composites
    XRD patterns of char after CONE test
    FT-IR spectra of EVA5 and EVA7 composites at 330 and 580 ℃
    Schematic diagram of flame-retardant mechanisms for EVA5 and EVA7 composites
    • Table 1. Formulations of EVA composites and test results of UL-94 and LOI

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      Table 1. Formulations of EVA composites and test results of UL-94 and LOI

      SampleEVA/%(in mass) ATH/%(in mass) ADP/%(in mass) LOI/%UL-94
      EVA14060034.5NR
      EVA24055534.7NR
      EVA340501036.8NR
      EVA440451537.4V-1
      EVA540402037.8V-0
      EVA640303039.2NR
      EVA740204042.8V-0
      EVA840154541.6NR
      EVA940105039.8NR
      EVA104006034.0NR
    • Table 2. Results of CONE test for EVA composites

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      Table 2. Results of CONE test for EVA composites

      SampleTTI/sPHRR/(kW·m-2) THR/(MJ·m-2) TSR/(m2·m-2) Residue mass/%
      EVA175167.9572.37417.7443.71
      EVA580253.0089.65928.1240.22
      EVA767399.9197.301895.2826.92
      EVA1045498.11106.142586.8416.71
    • Table 3. TG data for ATH, ADP, EVA,and EVA composites

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      Table 3. TG data for ATH, ADP, EVA,and EVA composites

      SampleT5%/℃ Tmax1/℃ Tmax2/℃ Residue mass at 800 ℃/%Theoretical mass of residue/%
      ATH250.7279.766.2
      ADP409.8466.818.8
      EVA342.5355.1472.30.0
      EVA1296.2324.9470.839.239.7
      EVA5306.4318.6471.231.830.2
      EVA7322.5326.5467.516.620.7
      EVA10362.8361.5467.33.411.3
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    Bo CHENG, Xiaohang AN, Dinghua LI, Rongjie YANG. Flame-retardant Properties and Transformation of Flame-retardant Mechanisms of EVA: Effect of ATH/ADP Ratio[J]. Journal of Inorganic Materials, 2024, 39(5): 509

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    Paper Information

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    Received: Oct. 30, 2023

    Accepted: --

    Published Online: Jul. 8, 2024

    The Author Email: LI Dinghua (dli@bit.edu.cn)

    DOI:10.15541/jim20230502

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