<trans-title xml:lang="en">Synthesis of Orthorhombic Black Phosphorus by Chemical Vapor Transport Method</trans-title>

Mingfu FU; Wen YANG; Jiabao LI; Shukang DENG; Qihang ZHOU; Xiaobo FENG; Peizhi YANG

doi:10.15541/jim20210805

Journal of Inorganic Materials, Volume. 37, Issue 10, 1102(2022)

Synthesis of Orthorhombic Black Phosphorus by Chemical Vapor Transport Method

Mingfu FU... Wen YANG, Jiabao LI, Shukang DENG, Qihang ZHOU, Xiaobo FENG and Peizhi YANG* |Show fewer author(s)

Key Laboratory of Renewable Energy Advanced Materials and Manufacturing Technology (Ministry of Education), Yunnan Normal University, Kunming 650500, China

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Figures & Tables(8)

1. Photos of orthorhombic BP synthesized with different mineralizer components

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2. Pictures of orthorhombic BP synthesized under different w(Sn/I₂) ratios and relationship between the yields of BP and w(Sn/I₂)

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3. XRD patterns (a) of BP with different w(Sn/I₂) and schematic diagram (b) of cell atoms and crystal planes of BP

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4. Raman characterizations of BP with different w(Sn/I₂), and optical microscope image of Raman using the surface scan and its vibration mode

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5. Component analysis of BP with different w(Sn/I₂)

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6. Surface morphologies and microstructures of BP with different ratios

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Table 1. Preparation of BP by different mineralizers
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Table 1. Preparation of BP by different mineralizers
Experiment number Experimental materials Mass ratio of mineralizer
1 RP@Sn@I₂ w(Sn/I₂)=2.51
2 RP@Pb@I₂ w(Pb/I₂)=3.96
3 RP@Sn@SnI₄ w(Sn/I)=2.61
4 RP@I₂ -
5 RP@Sn@SnCl₂ w(Sn/Cl)=9.29
6 RP@SnI₄ w(Sn/I)=0.23

Table 2. Synthesis of BP via diverse mass ratios of w(Sn/I₂)
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Table 2. Synthesis of BP via diverse mass ratios of w(Sn/I₂)
Experiment number Red phosphorus/mg w(Sn/I₂)
7 400 56.77
8 400 31.39
9 400 20.84
10 400 9.20
11 400 3.18
12 400 1.17
13 400 0.47
14 400 0.41

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Mingfu FU, Wen YANG, Jiabao LI, Shukang DENG, Qihang ZHOU, Xiaobo FENG, Peizhi YANG. Synthesis of Orthorhombic Black Phosphorus by Chemical Vapor Transport Method[J]. Journal of Inorganic Materials, 2022, 37(10): 1102

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