Journal of Inorganic Materials, Volume. 39, Issue 5, 531(2024)
Currently, the preparation of MgAl1.9Ga0.1O4 transparent ceramics which possess excellent optical properties, is still relying on combining aqueous gel-casting and prolonged pressureless pre-sintering. In this work, MgF2 was used as a sintering additive, and densification process of pressureless pre-sintering was adjusted by a transient liquid phase. MgAl1.9Ga0.1O4 transparent ceramics with different sizes were prepared by dry pressing, pressureless pre-sintering, and hot isostatic pressing treatment. The effects of MgF2 additive on microstructure, optical, and mechanical properties of the samples were systematically analyzed. The results indicated that MgF2 melted at ~1230 ℃, contributing to increase of density and grain size of the pre-sintered body, while the residual MgF2 was oxidized to MgO and dissolved into the MgAl1.9Ga0.1O4 lattice in the subsequent sintering process. The 2.04 mm thick transparent ceramic sample with 0.20% (in mass fraction) MgF2 has an in-line transmittance of 76.5%-83.4% in the UV and visible regions. Moreover, the sample has high optical quality with low scattering on incident light. In addition, the characteristic flexural strength of this ceramics is 167.1 MPa, which is close to that of the fine-grained MgAl2O4 transparent ceramics, but the Weibull modulus (8.81±0.29) is higher. This study provided a new option for the preparation of large MgAl1.9Ga0.1O4 transparent ceramic materials with good optical properties.
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Zhaoyang LÜ, Yong XU, Jiuyan YANG, Guangsheng TU, Bingtian TU, Hao WANG.
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Received: Dec. 21, 2023
Accepted: --
Published Online: Jul. 8, 2024
The Author Email: WANG Hao (shswangh@whut.edu.cn)