Journal of Synthetic Crystals, Volume. 53, Issue 11, 1972(2024)

Kinetic Study on the Sintering Process of Zn1.1Ga1.8Ge0.1O4 Transparent Ceramics

WANG Kaiqiang... YANG Kang, JING Zhengyang, CHEN Bowen, TU Bingtian and WANG Hao* |Show fewer author(s)
Author Affiliations
  • State Key Lab of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
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    Spinel-type Zn1.1Ga1.8Ge0.1O4 is an excellent host material for dielectric and long-persistent luminescent ceramics. It is helpful to expand application when the transparent ceramics is fabricated. In this paper, the pressureless sintering kinetics of Zn1.1Ga1.8Ge0.1O4 ceramics were studied. The results show that both densification and grain growth are controlled by the grain boundary diffusion of O2-. The activation energy for densification in the intermediate sintering stage is determined as (426±35) kJ/mol, while the activation energy for grain growth in the final sintering stage is calculated as (439±14) kJ/mol. When the combination of sintering parameters is optimized to enter into the so-called “sintering window”, the favorable microstructure of the pressureless-sintered body is obtained. After hot isostatic pressed at high temperature, Zn1.1Ga1.8Ge0.1O4 transparent ceramics with optical transmission ranging from 0.3 μm to 9 μm and in-line transmittance of 81.2% at 2.5 μm are prepared.

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    WANG Kaiqiang, YANG Kang, JING Zhengyang, CHEN Bowen, TU Bingtian, WANG Hao. Kinetic Study on the Sintering Process of Zn1.1Ga1.8Ge0.1O4 Transparent Ceramics[J]. Journal of Synthetic Crystals, 2024, 53(11): 1972

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    Paper Information

    Category:

    Received: Sep. 16, 2024

    Accepted: Jan. 2, 2025

    Published Online: Jan. 2, 2025

    The Author Email: Hao WANG (shswangh@whut.edu.cn)

    DOI:

    CSTR:32186.14.

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