Spectroscopy and Spectral Analysis, Volume. 42, Issue 8, 2444(2022)

PARAFAC and FRI Preferred 3D Fluorescence Extraction Time of Dissolved Organic Matter

Jun YI1,*... Guang YANG2,2;, Hong-wei PAN2,2; *;, Li-li ZHAO1,1;, Hong-jun LEI2,2;, Wen-bin TONG2,2; and Li-li SHI2,2; |Show fewer author(s)
Author Affiliations
  • 11. Henan Academy of Environmental Protection Sciences, Zhengzhou 450045, China
  • 22. College of Water Conservancy, North China University of Water Resources and Electric Power, Zhengzhou 450046, China
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    Figures & Tables(10)
    3D fluorescence spectrogram of humic acid under centrifugal extraction
    3D fluorescence spectrogram of humic acid under Oscillating extraction
    Variation of fluorescence region integration values under two extraction methods(a): Changes of regional integral values in centrifugal extraction;(b): Changes of regional integral values in oscillatory extraction
    Variation of Fmax values under two extraction methods(a): Changes of regional integral values in centrifugal extraction; (b): Changes of regional integral values in oscillatory extraction
    Fluorescence components of humic acid under the two extraction methods by PARAFAC model
    Correlation analysis of DOM components in humic acid(a): Correlation analysis of regional integral values by FRI method; (b): Correlation analysis of Fmax values by PARAFAC method
    Principle component analysis of DOM components in humic acid(a): Principle component analysis of Fmax values by PARAFAC method;(b): Principle component analysis of regional integral values under FRI method
    • Table 1. Fluorescent integral area

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      Table 1. Fluorescent integral area

      区域所代表有机物类型激发波长/nm发射波长/nm
      类腐殖酸250~450380~550
      类富里酸220~250380~550
      类色氨酸220~250330~380
      类络氨酸220~250280~330
      微生物代谢产物250~450280~380
    • Table 2. Characteristics of fluorescent component in humic acid DOM

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      Table 2. Characteristics of fluorescent component in humic acid DOM

      组分Ex/Em(nm)物质及描述文献中数值/nm
      C1270(340)/440生物可降解类腐殖质[14,15]265(360)/450
      C2245/410微生物类富里酸类物质[16,17]235/408
      C3290 (405)/495未定义类腐殖酸类物质[18,19](285/395)/497
    • Table 3. Best extraction time results under two extraction methods

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      Table 3. Best extraction time results under two extraction methods

      FRIPARAFAC
      组分名称离心/min振荡/h组分名称离心/min振荡/h
      P14521C14521
      P24512C24512
      P34512C34539
      P44512总量4512
      P54512
      总量4512
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    Jun YI, Guang YANG, Hong-wei PAN, Li-li ZHAO, Hong-jun LEI, Wen-bin TONG, Li-li SHI. PARAFAC and FRI Preferred 3D Fluorescence Extraction Time of Dissolved Organic Matter[J]. Spectroscopy and Spectral Analysis, 2022, 42(8): 2444

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    Paper Information

    Category: Orginal Article

    Received: Mar. 4, 2022

    Accepted: --

    Published Online: Mar. 17, 2025

    The Author Email: YI Jun (4058978@qq.com)

    DOI:10.3964/j.issn.1000-0593(2022)08-2444-08

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