Journal of Inorganic Materials, Volume. 37, Issue 6, 676(2022)

Microstructure and Thermal Quenching Characteristics of Na1-xMxCaEu(WO4)3 (M=Li, K) Red Phosphor

Xufeng GUAN... Guifang LI* and Yunge WEI |Show fewer author(s)
Author Affiliations
  • School of Advanced Materials and Nano Technology, Xidian University, Xi'an 710071, China
  • show less
    Figures & Tables(9)
    XRD patterns of phosphors
    Rietveld refinement XRD patterns of phosphors
    Excitation spectra of LiCaEu(WO4)3, NaCaEu(WO4)3 and KCaEu(WO4)3 phosphors monitored at 617 nm
    Emission spectra of phosphors and intensity contrast diagram of phosphors
    CIE chromaticity diagram of NaCaEu(WO4)3, Na0.7K0.3CaEu(WO4)3 and LiCaEu(WO4)3 phosphors
    Decay curves of NaCaEu(WO4)3, Na0.7K0.3CaEu(WO4)3 and LiCaEu(WO4)3 phosphors (λex=395 nm, λem=617 nm)
    Emission spectra of phosphors at different temperatures (λex=395 nm) (a-c), plot of ln(I0/IT-1) versus 1/(kT) (d) and schematic illustration of a configuration coordinate diagram of the thermal quenching process (e)
    • Table 1. Structure parameters of LiCaEu(WO4)3, NaCaEu(WO4)3 and KCaEu(WO4)3

      View table
      View in Article

      Table 1. Structure parameters of LiCaEu(WO4)3, NaCaEu(WO4)3 and KCaEu(WO4)3

      MaterialsCrystal systemSpace groupa=b/nm c/nm V/nm3α=β=γRwp/% R/%pχ2
      LiCaEu(WO4)3TetragonalI41/a 0.5230570(26)1.1319686(43)0.309694(8)90°8.617.662.438
      NaCaEu(WO4)3TetragonalI41/a 0.5255477(32)1.1393990(48)0.314702(5)90°7.685.951.468
      KCaEu(WO4)3TetragonalI41/a 0.5273337(35)1.1479226(52)0.319357(6)90°7.946.171.315
    • Table 2. CIE chromaticity coordinates and color purities of NaCaEu(WO4)3, Na0.7K0.3CaEu(WO4)3 and LiCaEu(WO4)3 phosphors

      View table
      View in Article

      Table 2. CIE chromaticity coordinates and color purities of NaCaEu(WO4)3, Na0.7K0.3CaEu(WO4)3 and LiCaEu(WO4)3 phosphors

      MaterialCIE chromaticity coordinateColor purity/%
      xy
      NaCaEu(WO4)30.65800.34196.07
      Na0.7K0.3CaEu(WO4)30.6610.33896.83
      LiCaEu(WO4)30.6650.33497.87
    Tools

    Get Citation

    Copy Citation Text

    Xufeng GUAN, Guifang LI, Yunge WEI. Microstructure and Thermal Quenching Characteristics of Na1-xMxCaEu(WO4)3 (M=Li, K) Red Phosphor [J]. Journal of Inorganic Materials, 2022, 37(6): 676

    Download Citation

    EndNote(RIS)BibTexPlain Text
    Save article for my favorites
    Paper Information

    Category: RESEARCH ARTICLE

    Received: Jul. 7, 2021

    Accepted: --

    Published Online: Jan. 10, 2023

    The Author Email: LI Guifang (gfli@mail.xidian.edu.cn)

    DOI:10.15541/jim20210426

    Topics