Laser & Optoelectronics Progress, Volume. 55, Issue 11, 111602(2018)

Low-Temperature Sintering and Properties of Ceramics Fabricated from YAG∶Ce 3+ Phosphor Powder

Xiaotong Xie**, Haitao Zhu, He Liu, Qinjiang He, and Renli Fu*
Author Affiliations
  • College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, Jiangsu 210016, China
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    Figures & Tables(18)
    Flow char of coating process
    Particle distributions of YAG∶Ce3+ phosphor powder
    SEM images of YAG∶Ce3+ phosphor powder. (a) Original particles; (b) particles after ball milling; (c) particles after coating
    UV-Vis absorption spectra of coated YAG∶Ce3+ phosphor powder
    Coating model of YAG∶Ce3+ phosphor powder particle
    Light illumination on spherical receiving surfaces of YAG∶Ce3+ phosphor powder particles before and after coating. (a) After TEOS coating; (b) before TEOS coating
    Light mapping of YAG∶Ce3+ ceramics excited by 460 nm blue light. (a) Non-excited state; (b) excited state
    Emission spectra
    Relative densities of YAG∶Ce3+ ceramics with different amounts of TEOS after inserting at 1475-1625 ℃ for 5 h
    Micro-morphologies of YAG ceramics after inserting at 1575 ℃ for 5 h. (a) Before coated with 2% TEOS; (b) after coated with 2% TEOS
    Relative densities of YAG ceramics sintered at 1400-1500 ℃ under different doping conditions
    Micro-morphologies of YAG ceramics sintered at different temperatures and and at different doping. (a) Cuo-TiO2 doped, 1450 ℃; (b) CuO doped, 1475 ℃
    Rockwell hardness of samples after sintering at different temperatures for 5 h
    Fracture toughness of samples after sintering at different temperatures for 5 h
    Rockwell hardness and fracture toughness of YAG ceramics doped with 2% CuO
    Rockwell hardness and fracture toughness of YAG ceramic doped with 2% CuO-TiO2
    • Table 1. Model size parameters and physical properties of TEOS-coated YAG∶Ce3+ phosphor powder particles[29-32]

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      Table 1. Model size parameters and physical properties of TEOS-coated YAG∶Ce3+ phosphor powder particles[29-32]

      MaterialSizePhysical parameter
      YAG∶Ce3+ phosphor powder particlesRadius: 1.5 μmn=2.1, α=0.82 mm-1
      TEOS coating-layerInner radius: 1.5 μmExternal radius: 1.6 μmn=1.6, α=0 mm-1
      Light source0.5 μm×0.5 μm×0.5 μmPower: 1 W, wavelength: 200 nm
      Spherical receiverInner radius: 3.6 μmExternal radius: 4.0 μmInner surface: perfect absorption
    • Table 2. Particle size and sintering properties of powder

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      Table 2. Particle size and sintering properties of powder

      TreatmentmodeParticle sized(0.5) /μmSinteringtemperate T /℃Linearshrinkage Ls /%Densityρ /(g·cm-3)Relativedensity /%
      Original particles22.305165012.3%4.1391.7
      Ball milling 24 h15.604165013.7%4.2193.5
      Grinding 2 h+ball milling 24 h3.182162514.6%4.3194.8
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    Xiaotong Xie, Haitao Zhu, He Liu, Qinjiang He, Renli Fu. Low-Temperature Sintering and Properties of Ceramics Fabricated from YAG∶Ce 3+ Phosphor Powder [J]. Laser & Optoelectronics Progress, 2018, 55(11): 111602

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    Paper Information

    Category: Materials

    Received: Apr. 17, 2018

    Accepted: May. 30, 2018

    Published Online: Aug. 14, 2019

    The Author Email: Xie Xiaotong (xiexiaotong1031@163.com), Fu Renli (renlifu@nuaa.edu.cn)

    DOI:10.3788/LOP55.111602

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