We have developed a new material system for the photon-gated hole burning:Zn-tetrabenzoporphin crotonic acid phenoxy resin, carried out various experiments forthe material and have a series of photon-gated holes at different wavelengthes with in aninhomogenously broadened absorption band at temperature of 20 K. We also dis cussrelative subjectes in some derail, such as, temperature affect, on hole, the hole lifetime,the photo-erasable performence of burnt holes, and the gating ratio G.