Chinese Journal of Quantum Electronics, Volume. 32, Issue 3, 371(2015)
Numerical simulation for polymer/fullerene bulk heterojunction solar cells
A numerical device model was introduced that consistently describes the current-voltage characteristics of polymer/fullerene bulk heterojunction solar cells. Bimolecular recombination and temperature and field dependent generation mechanism of free charges were also presented. It was demonstrated that in poly based solar cells space-charge effects only play a minor role, leading to a relatively constant electric field in the device. Furthermore, at short-circuit conditions only 7% of all free carriers are lost due to bimolecular recombination. The model predicts that an increased hole mobility together with a reduction of the acceptor strength of 0.5 eV will lead to a maximum attainable efficiency of 5.5% in the PPV/PCBM-based solar cells.
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XIAO Feng, YUAN Shitao, HUANG Zhixiang, WU Xianliang. Numerical simulation for polymer/fullerene bulk heterojunction solar cells[J]. Chinese Journal of Quantum Electronics, 2015, 32(3): 371
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Received: Aug. 6, 2014
Accepted: --
Published Online: May. 29, 2015
The Author Email: Feng XIAO (308226472@qq.com)