Associated radioactive mines are widely distributed in China, with many industries, complex processes and technologies, close relationship with the public, and great impact on the radiation environment. They are relatively weak links in nuclear and radiation safety supervision. In the process of implementing the upper level document, some specific problems have to be faced, such as the definition of associated radioactive ore, the scope of associated radioactive ore development and utilization, etc. In the field of radiation environment supervision, there are issues such as effluent and radiation environment monitoring specifications that need to be solved. In particular, the treatment and disposal of associated radioactive solid waste is the key problem that currently restricts the sustainable development of associated radioactive ore development and utilization. The second national census of pollution sources reported the cumulative storage of associated radioactive solid waste in the country, and the radiation environment supervision situation is grim. In the scope of associated radioactive mines and some problems encountered in the supervision of radiation environment, this study aims to formulate a reasonable and feasible supervision system for associated radioactive mines, standardize supervision and management activities, and ensure the safety of the radiation environment according to scientific management methods, combined with the practice of supervision of associated radioactive mines. Suggestions on the definition of the scope and development and utilization of associated radioactive mines and the management of the inventory are put forward for solving the radiation environment supervision system with consideration on the storage period of associated radioactive solid waste, the management of nearby centralized disposal and disposal facilities. As the radiation environmental supervision of associated radioactive mines is still a relatively weak area in nuclear and radiation safety supervision system in China, radiation environmental impact assessment and environmental radiation self-monitoring need to be strengthened.