Journal of the Chinese Ceramic Society, Volume. 50, Issue 5, 1257(2022)
Preparation of Cu2ZnSnS4 Thin Films Solar Cells Based on Magnetron Sputtering
In order to solve a problem of Sn-loss and reduce the thickness of MoS2 during the sulfurization process, the oxygen containing Cu-Zn-Sn precursor thin films were prepared on Mo-coated soda lime glasses via magnetron sputtering ZnO/SnO2/Cu. The results show that the Sn-loss and the formation of MoS2 are well inhibited by the utilization of SnO2 and ZnO. The single-phase CZTS absorbed thin films with the smooth surface, dense grains and good crystal structure can be prepared at 590 ℃. Also, the CZTS solar cells from oxygen containing precursors annealed at 590 ℃ have an optimum power conversion efficiency (PCE) of 5.12% with an open circuit voltage of 590 mV, a short circuit current density of 22.09 mA/cm2 and a fill factor of 39.28%.
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LI Xinyu, ZHANG Daoyong, LI Xiang, LI Qiulian, LIU Xin, WANG Shurong. Preparation of Cu2ZnSnS4 Thin Films Solar Cells Based on Magnetron Sputtering[J]. Journal of the Chinese Ceramic Society, 2022, 50(5): 1257
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Received: Jul. 2, 2021
Accepted: --
Published Online: Nov. 23, 2022
The Author Email: Xinyu LI (Lixinyu@aliyun.com)
CSTR:32186.14.