NUCLEAR TECHNIQUES, Volume. 46, Issue 6, 060202(2023)

Effect of trace Y on mechanical and oxidation properties of FeCrAl alloy cladding

Yang LIU1,2、*, Haibin MA1,2, Lixiang WU1,2, Daxi GUO1,2, Jun YAN1,2, Rongkun YANG1,2, Qisen REN1,2, and Jiaxiang XUE1,2
Author Affiliations
  • 1China Nuclear Power Technology Research Institute, ATF Department, Shenzhen 518000, China
  • 2High-safety Accident Tolerant Fuel Technical Engineering Laboratory, Shenzhen 518000, China
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    Background

    FeCrAl alloy cladding, as an accident tolerant fuel (ATF) mid-term commercial technology approach, has received extensive attention.

    Purpose

    This study aims to investigate the effect of trace Y on the internal pressure burst and oxidation properties of FeCrAl alloy cladding.

    Methods

    Firstly, the crystalline grain size and micro-morphologies of FeCrAl and FeCrAlY alloy cladding samples were observed by optical microscope. Internal pressure burst and high temperature oxidation tests were carried out by burst test equipment and thermo-gravimetric analyzer with a moisture generator. Then, X-ray diffractometry (XRD), scanning electron microscope (SEM) and energy dispersive spectrometer (EDS) were employed to analyze the composition of oxidation products, surface and cross-sectional micro-morphologies of FeCrAl and FeCrAlY alloy cladding samples before and after high-temperature stream oxidation and the distribution of elements on the surface oxidation products.

    Results

    The results show that trace Y is mainly dissolved in the FeCrAl alloy matrix, and no Fe-Y phase is formed. The inclusion of Y do not change the burst strength and the rupture opening morphology at room temperature (RT) to 1 000 ℃, and the high-temperature steam oxidation resistance of FeCrAl alloy cladding is significantly improved by the trace Y. Under the condition of steam oxidation at 800 ℃, 1 000 ℃ and 1 200 °C for 8 h, the oxidation weight gain of FeCrAlY alloy cladding decrease by 65.1%, 60.0% and 31.5%, respectively. Compared with the single Al2O3 oxide film on the surface of FeCrAl alloy cladding, the Y-containing composite oxide film with lower internal stress, higher compactness and better adhesion with the substrate is formed on the surface of FeCrAlY alloy cladding.

    Conclusions

    Therefore, the addition of trace Y do not change the burst properties of FeCrAl alloy cladding, however, the high-temperature steam oxidation resistance of FeCrAl alloy cladding is significantly improved.

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    Yang LIU, Haibin MA, Lixiang WU, Daxi GUO, Jun YAN, Rongkun YANG, Qisen REN, Jiaxiang XUE. Effect of trace Y on mechanical and oxidation properties of FeCrAl alloy cladding[J]. NUCLEAR TECHNIQUES, 2023, 46(6): 060202

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    Paper Information

    Category: Research Articles

    Received: Nov. 9, 2022

    Accepted: --

    Published Online: Jul. 5, 2023

    The Author Email:

    DOI:10.11889/j.0253-3219.2023.hjs.46.060202

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