Bulletin of the Chinese Ceramic Society, Volume. 42, Issue 11, 4131(2023)

Fabrication and Properties of Infrared Gradient Refractive Index GeS2-In2S3-CsCl Chalcogenide Glass-Ceramics

LIU Hongjun1,2、*, LI Chengkang1,2, ZHOU Gangjie1,2, CHEN Jinjin1,2, and LIN Changgui1,2
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  • 2[in Chinese]
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    Gradient refractive index infrared imaging system can greatly reduce the sizeweight and cost of system while maintaining imaging performancewhich is expected to advance the development of infrared imaging system towards lightweight and compactness. Howevercurrently available infrared gradient refractive index optical materials are not accessible. Based on 65GeS2-25In2S3-10CsCl chalcogenide glassa gradient temperature field was used to thermally induce the precipitation of axially gradient-distributed β-In2S3 nanocrystals to produce a gradient refractive index transparent chalcogenide glass-ceramics. The results show that the precipitated β-In2S3 crystals are polycrystalline structures composed of nanocrystals with different crystallographic orientationswith a size of about 25 nmand the size and number of crystals are closely related to gradient temperature field. The gradient refractive index chalcogenide glass-ceramics still maintain good transmission in long-wave infraredand their maximum refractive index difference Δn reaches 0.047 at 10 μm.

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    LIU Hongjun, LI Chengkang, ZHOU Gangjie, CHEN Jinjin, LIN Changgui. Fabrication and Properties of Infrared Gradient Refractive Index GeS2-In2S3-CsCl Chalcogenide Glass-Ceramics[J]. Bulletin of the Chinese Ceramic Society, 2023, 42(11): 4131

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    Paper Information

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    Received: Jul. 24, 2023

    Accepted: --

    Published Online: Dec. 11, 2023

    The Author Email: Hongjun LIU (kqwdzr@qq.com)

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