Spectroscopy and Spectral Analysis, Volume. 37, Issue 3, 881(2017)
Preparation of Rubber Accelerator Tetrabenzylthiuramdisulfide and Its Spectral Analysis
In the study, rubber accelerator tetrabenzylthiuramdisulfide (TBzDT) was synthesized with two-step method with hydrogen peroxide as oxidant firstly. TBzDT was detected and characterized with XRD, FT-IR, TG-DTA. Its micro-structure was revealed. Chemical bond types into TBzDT molecule were revealed with FT-IR. TBzDT phase composition and structure were given by crystallographic data from XRD detecting such as cell parameters, crystal face index. The phase composition and qualitative identification of TBzDT structure were completed. Two kinds of information were detected with TG-DTA as to quality change and thermal effect. TBzDT phase transition and decomposition temperature were 142.5, 200.9 ℃ respectively. The decomposition temperature of TBzDT was relevtively high. It could provided reference with research on rubber vulcanizing properties by TBzDT on rubber vulcanizing machine. A little SC2 contained into TBzDT was revealed by FTIR, TG-DTA from different sides.
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JIA Tai-xuan, ZHANG Nan, GUO Yao, LU You-chang, TIAN Da-yong, LI Hong-liang. Preparation of Rubber Accelerator Tetrabenzylthiuramdisulfide and Its Spectral Analysis[J]. Spectroscopy and Spectral Analysis, 2017, 37(3): 881
Received: Jun. 29, 2015
Accepted: --
Published Online: Jun. 20, 2017
The Author Email: Tai-xuan JIA (jiataixuan@163.com)