Journal of Inorganic Materials, Volume. 36, Issue 8, 865(2021)

Mechanism of the Magnetic and Specific-heat Anomalies in Rare-earth Dodecaborides RB12 (R=Tb-Tm): an Effect of Crystal-field-splitting Order Parameter

Jingsan HU1... Jianfei GU1, and Weiyi ZHANG12,* |Show fewer author(s)
Author Affiliations
  • 11. School of Physics, Nanjing University, Nanjing 210093, China
  • 22. National Laboratory of Solid State Microstructures and Department of Physics, Nanjing University, Nanjing 210093, China
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    Rare-earth dodecaborides RB12 (R=Tb, Dy, Ho, Er, Tm) are all characterized by a controversial and unresolved magnetic and specific-heat anomaly at low temperature (TC≈3-22 K) except LuB12 with closed f-shell. Although the bump feature in magnetic susceptibilities resembles that of antiferromagnetically ordered R3+ ions, no definite magnetic structure was identified by either neutron scattering or Mössbauer spectra. The anomalies in susceptibilities, entropy, and low temperature neutron diffraction pattern all pointed to the amplitude-modulated nature of complex magnetic structure. In view of the rather small crystal-field-splitting energies of the order of meV, we propose to treat crystal-field-splitting (CFS) energy as an order parameter rather than a quantum mechanical quantity. In this way, we found that not only the magnetic and specific-heat anomalies can be explained properly by a gradual quenching of R orbital moments, but also the low temperature satellite peaks of neutron scattering spectra can be understood in terms of the spontaneously (111) dimerised structure and inelastically absorbed rattling phonon modes.

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    Jingsan HU, Jianfei GU, Weiyi ZHANG. Mechanism of the Magnetic and Specific-heat Anomalies in Rare-earth Dodecaborides RB12 (R=Tb-Tm): an Effect of Crystal-field-splitting Order Parameter [J]. Journal of Inorganic Materials, 2021, 36(8): 865

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    Paper Information

    Category: RESEARCH ARTICLE

    Received: Nov. 3, 2020

    Accepted: --

    Published Online: Dec. 8, 2021

    The Author Email: ZHANG Weiyi (wyzhang@nju.edu.cn)

    DOI:10.15541/jim20200623

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