Journal of Inorganic Materials, Volume. 36, Issue 7, 685(2021)
Research Progress on the Preparation and Characterization of Ultra Refractory TaxHf1-xC Solid Solution Ceramics
Peng XIAO1, Yulin ZHU2, Song WANG1、*, Yiping YU1, and Hao LI1
Author Affiliations
11. Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, College of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China22. Unit 32382 of the PLA, Wuhan 430311, Chinashow less
TaxHf1-xC(0 4000 K), high hardness (~ 30 GPa), low coefficient of thermal expansion, excellent oxidation resistance, and excellent ablation resistance. Over the past decades, some extreme conditions required for aerospace industry have greatly promoted the development of TaxHf1-xC materials, and dozens of literatures were published in this area. In this paper, the research progress of TaxHf1-xC solid solution ceramics was introduced in terms of powder synthesis techniques, densification methods and mechanism, mechanical properties at room temperature, thermophysical properties, oxidation and ablation resistance. Advantages and disadvantages of three common techniques (solid solution between metal carbides, carbonization reaction of metals, and carbothermal reduction of metal oxides) for synthesizing TaxHf1-xC powder as well as the difficulties in densification of TaxHf1-xC solid solution ceramics were analyzed. Influence of sintering process on microstructure and mechanical properties at room temperature of TaxHf1-xC solid solution ceramics was discussed briefly. The hardness, elastic modulus, KIC, melting point, thermal conductivity, coefficient of thermal expansion, oxidation and ablation behavior of TaxHf1-xC solid solution ceramics with different Ta/Hf ratios were summarized. It revealed that TaxHf1-xC solid solution ceramics will obtain a good performance on both mechanical properties and oxidation resistance when Ta/Hf was approximate 1. Furthermore, the remaining challenges and future outlook of TaxHf1-xC solid solution ceramics were also addressed.