Acta Physica Sinica, Volume. 69, Issue 11, 118501-1(2020)

Research progress of stability of luminous lead halide perovskite nanocrystals

Qin-Hua Fan1, Yan-Qing Zu2, Lu Li2, Jin-Fei Dai2, and Zhao-Xin Wu1,2、*
Author Affiliations
  • 1Ningbo Exciton Innovation Materials Research Institute Co., Ltd., Ningbo 315000, China
  • 2Key Laboratory of Photonics Technology for Information of Shaanxi Province, School of Electronic and Information Engineering, Xi’an Jiaotong University, Xi’an 710049, China
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    The lead halide perovskite nanocrystals (NCs) have become more ideal luminescent materials due to the excellent properties such as narrow emission linewidth, photoluminescence quantum yield (PLQY), adjustable spectrum and facile preparation in comparison with traditional II-VI or III-V group semiconductor NCs. Until now, the external quantum efficiency (EQE) of light-emitting diode (LED) devices using perovskite NCs as emitting layers, has reached > 20%. This optical performance is close to that of the commercially available organic LED, which shows their great potential applications in solid state lighting and panel displaying. However, when perovskite NCs suffer light, heat and polar solvent, they exhibit the poor stability owing to the intrinsic ion properties of perovskite, and highly dynamic interface between NCs and ligands as well as the abundant defects on the surface of NCs. Therefore, how to elevate their stability is a key and urgent problem. In this review, three methods to improve the stability of NCs are summarized: 1) In situ surface passivation with tight-binding or protonation-free sole ligands such as oleic acid (OA), oleamine (OAM), dodecyl benzene sulfonic acid, octylphosphonic acid, sulfobetaines, lecithin and two ligands such as 2-hexyldecanoic acid/OAM, bis-(2,2,4-trimethylpentyl)phosphinic acid/OAM as well as three ligands such as OA/OAM/Al(NO3)3·9H2O, OA/OAM/tris(diethylamino)phosphine); the postsynthetic ligand exchange or passivation with 1-tetradecyl-3-methylimidazolium bromide, 2-aminoethanethiol, silver-trioctylphosphine complex and n-dodecylammonium thiocyanate; 2) the doping of Cs+ by FA+, Na+ and the doping of Pb2+ by Zn2+, Mn2+, Cd2+, Sr2+, Sb3+ in perovskite NCs; 3) the surface coating with inorganic oxides (SiO2, ZrO2, Al2O3, NiOx), inorganic salts (NaNO3, NH4Br, PbSO4, NaBr, RbBr, PbBr(OH)), porous materials (mesoporous silica, zeolite-Y, lead-based metal-organic frameworks), polymer materials (polystyrene, poly(styrene-ethylene-butylene-styrene, poly(laurylmethacrylate), poly(maleic anhydride-alt-1-octadecene), polyimide, poly(n-butyl methacrylate-co-2-(methacryloyloxy)ethyl-sulfobetaine)). Besides, we make some suggestions to further improve the stability of NCs as follows: 1) Developing the surface ligands with good dispersity and multi-coordination groups; 2) theoretically studying the influence of ion doping on the structure and stability; 3) realizing the stable and conductive metal oxides shell for uniform and compact encapsulation of NCs core. In a word, these conventional methods can enhance the stability of NCs to a certain extent, which fail to meet the requirements for practical application, so more efforts will be needed in the future.

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    Qin-Hua Fan, Yan-Qing Zu, Lu Li, Jin-Fei Dai, Zhao-Xin Wu. Research progress of stability of luminous lead halide perovskite nanocrystals[J]. Acta Physica Sinica, 2020, 69(11): 118501-1

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    Paper Information

    Received: Nov. 20, 2019

    Accepted: --

    Published Online: Dec. 2, 2020

    The Author Email:

    DOI:10.7498/aps.69.20191767

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