Spectroscopy and Spectral Analysis, Volume. 29, Issue 12, 3173(2009)

Trace Detection of Ammonia at 1.531μm

JIA Hui1,2、*, GUO Xiao-yong3, CAI Ting-dong4,5, ZHAO Wei-xiong4,5, WANG Lei4,5, TAN Tu4,5, ZHANG Wei-jun4,5, and GAO Xiao-ming4,5
Author Affiliations
  • 1[in Chinese]
  • 2[in Chinese]
  • 3[in Chinese]
  • 4[in Chinese]
  • 5[in Chinese]
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    A compact instrument based on the off-axis integrated-cavity output spectroscopy(ICOS) technology was developed for sensitive measurements of gas mixing ratios(ammonia in air) at room temperature by using fiber-coupled distributed feedback(DFB) diode laser operating at 1.531μm. The absorption line of ammonia at 6528.764cm-1 was chosen for trace detection. The mirrors' effective reflectivity R2 of 0.9969 was first calibrated by carbon dioxide under this condition, and the avity 35.8cm in length as an absorption cell could yield an optical path of presumably 115.46m. As a result, a minimum detectable concentration of approximately 2.66ppmv(S/N~3) at the total pressure of 100 torr was obtained. Then the lock-in a mplifier was added in the system to acquire the econd armonic signal by ombination of wavelength modulation technology, which could better suppress background noise and improve the signal-to-noise ratio, and a detection limit of 0.293ppmv(S/N~3) was achieved eventually. This work demonstrated the potential of the system for a range of atmospheric species sensing in the future.

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    JIA Hui, GUO Xiao-yong, CAI Ting-dong, ZHAO Wei-xiong, WANG Lei, TAN Tu, ZHANG Wei-jun, GAO Xiao-ming. Trace Detection of Ammonia at 1.531μm[J]. Spectroscopy and Spectral Analysis, 2009, 29(12): 3173

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    Paper Information

    Received: Dec. 19, 2008

    Accepted: --

    Published Online: Jan. 4, 2010

    The Author Email: Hui JIA (jiahui@mail.ustc.edu.cn)

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