Optics and Precision Engineering, Volume. 30, Issue 16, 1915(2022)
Preparation and photodetection performance of ZnO nanorods/Bi2S3 quantum dots heterojunction
In order to obtain a ZnO-based broadband photodetector with a multi-band response, ZnO is coupled with other narrow-bandgap semiconductors to construct the heterojunction. In this study, ZnO nanorods (NRs) arrays were first grown on FTO substrates through the hydrothermal process. Then, Bi2S3 quantum dots (QDs) were synthesized on the surface of ZnO NRs via the successive ionic layer absorption reaction method, thereby successfully constructing the ZnO NRs/Bi2S3 QDs heterojunction. The micro-morphology and elemental composition of as-prepared samples were characterized using a scanning electron microscope and energy dispersive spectrometer. The results show that the Bi2S3 QDs are uniformly and densely attached to the surface of ZnO NRs that are slightly curved and partially intertwined at the top. Then, a broadband photodetector was fabricated based on the as-prepared heterojunction. In addition, the photodetector based on the ZnO NRs/Bi2S3 QDs heterojunction can operate without an external power source, indicating that the photodetector has a self-powered feature. Compared with the ZnO NRs photodetector, the maximum photocurrent of the ZnO NRs/Bi2S3 QDs photodetector under UV light irradiation increases by approximately 0.065 mA. This is mainly because the type II band alignment between ZnO and Bi2S3 increases the separation efficiency of photogenerated charge carriers. Furthermore, the ZnO NRs/Bi2S3 QDs photodetector has excellent detection capability for visible light, exhibiting excellent cycle stability when irradiated by blue (470 nm) and green light (530 nm).
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Jianhua ZHU, Ping RONG, Shuai REN, Xinyu GUO, Shiyong GAO. Preparation and photodetection performance of ZnO nanorods/Bi2S3 quantum dots heterojunction[J]. Optics and Precision Engineering, 2022, 30(16): 1915
Category: Modern Applied Optics
Received: Apr. 21, 2022
Accepted: --
Published Online: Sep. 22, 2022
The Author Email: GAO Shiyong (gaoshiyong@hit.edu.cn)