The present work investigates the effects of different buffer layers on the performance of blue organic light-emitting diodes (OLEDs), and compares them with the device with no buffer layer.Two kinds of blue OLEDs with 4,4’-bis(2,2’-diphenyl vinyl)-1,1’-biphenyl (DPVBi) as the emitting layer, N,N’-bis-(1-naphthyl)-N,N’-1-diphenyl-1,1’-biphenyl-4,4’-diamine (NPB) as the hole transporting layer, and copper phthalocyanine (CuPc) and poly(3,4-ethylenedioxythiophene)∶poly(styrenesulphonate) PEDOT∶PSS as the hole injection layer respectively were fabricated with the structures of ITO/CuPc/NPB/DPVBi/BCP/Alq3/Al and ITO/PEDOT∶PSS/NPB/DPVBi/BCP/Alq3/Al.Moreover, the effects of different preparation technology of CuPc on the performance of OLEDs were also investigated.It was found that the performance of the devices with a hole injection layer is better than that of the device without any hole-injection layer.Although the luminance and efficiency of the water-soluble CuPc based device are worse than that of the device with thermally evaporated CuPc, but better than that of the device with water-soluble PEDOT∶PSS.So the water-soluble CuPc is a good hole injection material because it is easier to fabricate the film than traditional CuPc.