Nano-Micro Letters, Volume. 17, Issue 1, 033(2025)

Optimization Strategies of Na3V2(PO4)3 Cathode Materials for Sodium-Ion Batteries

Jiawen Hu1, Xinwei Li1, Qianqian Liang1, Li Xu1, Changsheng Ding1、*, Yu Liu2, and Yanfeng Gao1、**
Author Affiliations
  • 1School of Materials Science and Engineering, Shanghai University, Shanghai 200444, People’s Republic of China
  • 2Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, People’s Republic of China
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    Na3V2(PO4)3 (NVP) has garnered great attentions as a prospective cathode material for sodium-ion batteries (SIBs) by virtue of its decent theoretical capacity, superior ion conductivity and high structural stability. However, the inherently poor electronic conductivity and sluggish sodium-ion diffusion kinetics of NVP material give rise to inferior rate performance and unsatisfactory energy density, which strictly confine its further application in SIBs. Thus, it is of significance to boost the sodium storage performance of NVP cathode material. Up to now, many methods have been developed to optimize the electrochemical performance of NVP cathode material. In this review, the latest advances in optimization strategies for improving the electrochemical performance of NVP cathode material are well summarized and discussed, including carbon coating or modification, foreign-ion doping or substitution and nanostructure and morphology design. The foreign-ion doping or substitution is highlighted, involving Na, V, and PO43- sites, which include single-site doping, multiple-site doping, single-ion doping, multiple-ion doping and so on. Furthermore, the challenges and prospects of high-performance NVP cathode material are also put forward. It is believed that this review can provide a useful reference for designing and developing high-performance NVP cathode material toward the large-scale application in SIBs.

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    Jiawen Hu, Xinwei Li, Qianqian Liang, Li Xu, Changsheng Ding, Yu Liu, Yanfeng Gao. Optimization Strategies of Na3V2(PO4)3 Cathode Materials for Sodium-Ion Batteries[J]. Nano-Micro Letters, 2025, 17(1): 033

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    Paper Information

    Category: Research Articles

    Received: Jun. 12, 2024

    Accepted: Sep. 1, 2024

    Published Online: Feb. 12, 2025

    The Author Email: Ding Changsheng (dingcs@shu.edu.cn), Gao Yanfeng (yfgao@shu.edu.cn)

    DOI:10.1007/s40820-024-01526-x

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