The confirmation of energy transfer from TTPP to Pc in binary molecules of TTPP-O-Pc and TTPP-O-(CH2)5-O-PC has been made by studying the luminescence and excitation spectra, and the two emission bands in the latter were distinguished. The nondegenerate four-wave mixing (NDFWM) was employed to investigate the relaxation processes of excited states (τ1) and charge transfer (τ2). The relaxation times of τ1 and τ2 were, for the first time, obtained to be 4.5 ps and 18.5 ps for TTPP-O-Pc, and 4.2 ps and 82 ps for TTPP-O-(CH2)5-O-Pc.