Journal of the Chinese Ceramic Society, Volume. 51, Issue 9, 2188(2023)
Nitrogen-Doped Porous Hard Carbon as an Anode for Fast-Charging Lithium-Ion Batteries
The limited capacity and long charging time of graphite-based anodes for lithium-ion batteries cannot meet ever-growing demands. Developing anodes with a high capacity and a fast charging ability becomes a hotspot of the present research. Herein, an N-doped porous hard carbon (N-HC) was prepared via dehydration reaction of sucrose and sulfuric acid and subsequent annealing in NH3/Ar. The diffusion coefficient of Li+ in N-HC reaches 9.0×10?傆b8 cm2·s?傆b1 due to the rich ultra-micropore structure (i.e., pore size < 0.75 nm) and the large interlayer spacing (i.e., 0.39 nm) in N-HC. The capacity of N-HC remains 704.0 mA·h·g-1 or 269.2 mA·h·g-1 after 680 or 1 400 cycles at 0.27 C or 2.7 C (1 C=370 mA·g?傆b1). The N-HC electrode can meet the requirement of fast charging lithium-ion battery, while the initial Coulomb efficiency needs to be improved.
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LI Shengyuan, YE Chuanren, WANG Yizhe, ZHU Yanwu. Nitrogen-Doped Porous Hard Carbon as an Anode for Fast-Charging Lithium-Ion Batteries[J]. Journal of the Chinese Ceramic Society, 2023, 51(9): 2188
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Received: Feb. 24, 2023
Accepted: --
Published Online: Oct. 7, 2023
The Author Email: Shengyuan LI (zhuyanwu@ustc.edu.cn)
CSTR:32186.14.