The transient SES double Stockes-line in ethylene glycol by using the picosecond pulse train generated by a Nd-glass laser system with frequency doubling KDP crystal is described. The central wavelengthes of the double Stockes lines are 6246.5A and 6288.64 A respectively. The double Stockes lines are included by the symmetric and asymmetric vibrations of (OH)2 group of ethylene glycol. SES double lines coinside with Raman spectrum of HO·CH2·OH2·OH quite well.