Journal of Advanced Dielectrics, Volume. 15, Issue 2, 2450019(2025)
Statistical model for the description of ferroelectric phase transitions in BaTiO3 and KNbO3
In this paper, based on the developed statistical-thermodynamic model, which is based on data on the local structure of the compound and taking into account the striction interaction caused by the large sizes of the Ba and K cations, the formation of ferroelectric phases in BaTiO3 and KNbO3 perovskites has been studied. Based on the modified eight-minimum model, it has been possible to qualitatively identify the factors that determine the features of the thermodynamic behavior of these crystals and to reproduce the process of formation of the whole set of phase states observed in BaTiO3 and KNbO3.
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Michael Ivliev, Konstantin Andryushin. Statistical model for the description of ferroelectric phase transitions in BaTiO3 and KNbO3[J]. Journal of Advanced Dielectrics, 2025, 15(2): 2450019
Category: Research Articles
Received: Mar. 19, 2024
Accepted: Jul. 1, 2024
Published Online: Feb. 18, 2025
The Author Email: Andryushin Konstantin (kpandryushin@gmail.com)