Frontiers of Optoelectronics, Volume. 13, Issue 3, 265(2020)

Polymer hole-transport material improving thermal stability of inorganic perovskite solar cells

Shaiqiang MU1,2, Qiufeng YE2,3, Xingwang ZHANG2,3, Shihua HUANG1、*, and Jingbi YOU2,3
Author Affiliations
  • 1Physics Department, Zhejiang Normal University, Jinhua 321004, China
  • 2Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China
  • 3Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
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    Cesium-based inorganic perovskite solar cells (PSCs) are paid more attention because of their potential thermal stability. However, prevalent salt-doped 2,2′,7,7′- tetrakis(N,N-dipmethoxyphenylamine)9,9′-spirobifluorene (Spiro-OMeTAD) as hole-transport materials (HTMs) for a high-efficiency inorganic device has an unfortunate defective thermal stability. In this study, we apply poly (3-hexylthiophene-2,5-diyl) (P3HT) as the HTM and design all-inorganic PSCs with an indium tin oxide (ITO)/SnO2/LiF/CsPbI3-xBrx/P3HT/Au structure. As a result, the CsPbI3-xBrx PSCs achieve an excellent performance of 15.84%. The P3HT HTM-based device exhibits good photo-stability, maintaining ~80% of their initial power conversion efficiency over 280 h under one Sun irradiation. In addition, they also show better thermal stability compared with the traditional HTM Spiro- OMeTAD.

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    Shaiqiang MU, Qiufeng YE, Xingwang ZHANG, Shihua HUANG, Jingbi YOU. Polymer hole-transport material improving thermal stability of inorganic perovskite solar cells[J]. Frontiers of Optoelectronics, 2020, 13(3): 265

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    Paper Information

    Category: RESEARCH ARTICLE

    Received: Apr. 22, 2020

    Accepted: May. 9, 2020

    Published Online: Nov. 25, 2020

    The Author Email: HUANG Shihua (huangshihua@zjnu.cn)

    DOI:10.1007/s12200-020-1041-z

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