Bulletin of the Chinese Ceramic Society, Volume. 42, Issue 11, 4136(2023)
Influence of Zinc Oxide on Structure and Properties of Glass-Ceramics and Solidification Mechanism of Heavy Metal Zinc
Using analytical pure reagents as raw materials to simulate zinc-containing smelting slagglass-ceramics were prepared by melting method. X-ray diffractionscanning electron microscopyand Raman spectroscopy were used as characterization methods, and the effect of different zinc oxide content on the formationcrystallizationphysical and chemical properties of glass-ceramics was explored. The results show that the main crystalline phase of glass-ceramics is cordieriteand the addition of a small amount of zinc oxide (less than 0.5%mole fractionsame as below) can enhance the glass-forming ability. As the zinc oxide content gradually increases (0.5%~20.0%)the integrity of glass network structure deterioratesand the viscosity of glass decreases. The main phase of glass-ceramics is transformed from cordierite to spineland the crystallinity and grain size of glass-ceramics increase. Consequentlythe bulk densityhardness and resistance to acid/alkali corrosion of glass-ceramics also increase. Heavy metal zinc has good curability in glass-ceramicsso the leaching concentration of zinc is much lower than the standard valueand leaching rate tends to be stable. This study provides a reference for the solidification of heavy metals through glass-ceramics.
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LI Nianzhe, ZHANG Yuxuan, CUI Xiutao, OUYANG Shunli. Influence of Zinc Oxide on Structure and Properties of Glass-Ceramics and Solidification Mechanism of Heavy Metal Zinc[J]. Bulletin of the Chinese Ceramic Society, 2023, 42(11): 4136
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Received: Jul. 21, 2023
Accepted: --
Published Online: Dec. 11, 2023
The Author Email: Nianzhe LI (1057532793@qq.com)
CSTR:32186.14.