Bulletin of the Chinese Ceramic Society, Volume. 42, Issue 11, 4136(2023)

Influence of Zinc Oxide on Structure and Properties of Glass-Ceramics and Solidification Mechanism of Heavy Metal Zinc

LI Nianzhe1、*, ZHANG Yuxuan1, CUI Xiutao1, and OUYANG Shunli1,2
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  • 1[in Chinese]
  • 2[in Chinese]
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    Using analytical pure reagents as raw materials to simulate zinc-containing smelting slagglass-ceramics were prepared by melting method. X-ray diffractionscanning electron microscopyand Raman spectroscopy were used as characterization methods, and the effect of different zinc oxide content on the formationcrystallizationphysical and chemical properties of glass-ceramics was explored. The results show that the main crystalline phase of glass-ceramics is cordieriteand the addition of a small amount of zinc oxide (less than 0.5%mole fractionsame as below) can enhance the glass-forming ability. As the zinc oxide content gradually increases (0.5%~20.0%)the integrity of glass network structure deterioratesand the viscosity of glass decreases. The main phase of glass-ceramics is transformed from cordierite to spineland the crystallinity and grain size of glass-ceramics increase. Consequentlythe bulk densityhardness and resistance to acid/alkali corrosion of glass-ceramics also increase. Heavy metal zinc has good curability in glass-ceramicsso the leaching concentration of zinc is much lower than the standard valueand leaching rate tends to be stable. This study provides a reference for the solidification of heavy metals through glass-ceramics.

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    LI Nianzhe, ZHANG Yuxuan, CUI Xiutao, OUYANG Shunli. Influence of Zinc Oxide on Structure and Properties of Glass-Ceramics and Solidification Mechanism of Heavy Metal Zinc[J]. Bulletin of the Chinese Ceramic Society, 2023, 42(11): 4136

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    Paper Information

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    Received: Jul. 21, 2023

    Accepted: --

    Published Online: Dec. 11, 2023

    The Author Email: Nianzhe LI (1057532793@qq.com)

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