Chinese Optics Letters, Volume. 12, Issue 5, 051601(2014)

Energy transfer mechanism in Er3+ doped fluoride glass sensitized by Tm3+ or Ho3+ for 2.7-\mu m emission

Feifei Huang, Xueqiang Liu, Weiwei Li, Lili Hu, and Danping Chen

Enhanced 2.7 \mu m emission is obtained in Er3+/Tm3+ and Er3+/Ho3+ codoped ZBYA glasses. Absorption and emission spectra are tested to characterize the 2.7 \mu m emission properties of Er3+/Tm3+ and Er3+/Ho3+ doped ZBYA glasses and a reasonable energy transfer mechanism of 2.7 \mu m emission between Er3+ and Tm3+Ho3+) ion is proposed. Codoping of Tm3+ or Ho3+ significantly reduces the lifetime of the Er3+: 4I13/2 level due to the energy transfer of Er3+:4I13/2 →Tm3+:3F4 or Er3+:4I13/2 →Ho3+: 5I7. Thus, the 2.7 \mu m emission is strengthened and the 1.5 \mu m emission is decreased accordingly especially in the Er3+/Tm3+ sample. The upconversion effects between the Er3+/Tm3+ and Er3+/Ho3+ doped ZBYA glasses are different attribute to the different energy transfer efficiencies. Both of the two codoped samples possess nearly equal large emission cross section (16.6 \times 10-21 cm-2) around 2.7 \mu m. The results indicate that this Er3+/Tm3+ or Er3+/Ho3+ doped ZBYA glass has potential applications in 2.7 -m laser.

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Feifei Huang, Xueqiang Liu, Weiwei Li, Lili Hu, Danping Chen. Energy transfer mechanism in Er3+ doped fluoride glass sensitized by Tm3+ or Ho3+ for 2.7-\mu m emission[J]. Chinese Optics Letters, 2014, 12(5): 051601

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Received: Dec. 31, 2013

Accepted: Mar. 5, 2014

Published Online: May. 6, 2014

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DOI:10.3788/col201412.051601

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