Bulletin of the Chinese Ceramic Society, Volume. 41, Issue 11, 3813(2022)
Crystallization and Mechanical Properties of Li2OAl2O3SiO2 Glass Ceramics with High Strength and SemiTransparency
It’s an urgent problem to improve the strength of Li2OAl2O3SiO2 glass ceramics by glass composition design and crystallization process control. In this paper, Li2OAl2O3SiO2 glass with specific composition was prepared by meltquenching method, and high strength semitranslucent glass ceramics were prepared by twostep heat treatment. Differential scanning thermal analysis shows that the glass transition temperature is 532 ℃ and there are multiple crystallization peaks. After heat treatment, Xray diffraction patterns prove that Li2Si2O5, LiAlSi3O8, LiAlSi4O10 as the main crystal phases are precipitated in the glass, petalite crystals gradually changes into spodumene crystal phases with the increase of heat treatment temperatures or durations, and average crystal sizes grow from 70 nm (heat treatment parameters: 750 ℃,0.5 h and 780 ℃, 10 h) to 340 nm (heat treatment parameters: 820 ℃, 0.5 h and 850 ℃, 4 h). The glass ceramics change from translucent to opacities. Glass ceramics have excellent mechanical properties, the maximum Vickers hardness is 9.15 GPa, the maximum ringonring load can reach 1 335 N, and the maximum simulated whole machine drop height can reach 162 cm. The glass ceramics can be used as backplane protection glass for mobile phone devices.
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ZHOU Weiwei, CHEN Bao, HAO Zhenbang, HE Guangyuan, ZHU Kaidi, LIU Jingzhong, ZHANG Fujun, ZHANG Jihong. Crystallization and Mechanical Properties of Li2OAl2O3SiO2 Glass Ceramics with High Strength and SemiTransparency[J]. Bulletin of the Chinese Ceramic Society, 2022, 41(11): 3813
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Received: May. 6, 2022
Accepted: --
Published Online: Dec. 26, 2022
The Author Email: Weiwei ZHOU (zww@jsrfsolar.cn)
CSTR:32186.14.