Chinese Journal of Lasers, Volume. 41, Issue 10, 1006002(2014)
Near-Infrared Spectroscopic Properties and Judd-Ofelt Theory Analysis of Er3+/Yb3+ Co-Doped Fluoride Particles
Er3+/Yb3+ ion co-doped fluoride particles are synthesized and analyzed by their absorption spectra. The influence of the substances, the calcination temperature, and the doping ratio of Er3+ and Yb3+ on the absorption of the synthesized materials are studied. By analyzing the spectra of the samples with the Judd-Ofelt (J-O) theory, the intensity parameters are obtained as Ω2=9.9887, Ω4=2.7333, Ω6=0.4868, respectively. The results show that the phonon assisted transition probability and the energy transfer efficiency increases after heat treatment of the samples. The best doping ratio of Er3+ and Yb3+ is 16. Analysis based on the Judd-Ofelt theory shows that the synthesized fluoride particles have low phonon energy and good absorption property in the near-infrared region after doping with Er3+ and Yb3+ ions. It can be used as a kind of good materials for near-infrared upconversion.
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[in Chinese]. Near-Infrared Spectroscopic Properties and Judd-Ofelt Theory Analysis of Er3+/Yb3+ Co-Doped Fluoride Particles[J]. Chinese Journal of Lasers, 2014, 41(10): 1006002
Category: materials and thin films
Received: Apr. 10, 2014
Accepted: --
Published Online: Aug. 26, 2014
The Author Email: (liuchuanlfc@163.com)